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About This Item
Empirical Formula (Hill Notation):
C5H15N2O4P
CAS Number:
Molecular Weight:
198.16
NACRES:
NA.24
PubChem Substance ID:
eCl@ss:
39110524
UNSPSC Code:
41116107
EC Number:
278-636-5
MDL number:
Beilstein/REAXYS Number:
8163399
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
mp
215 °C
application(s)
agriculture
environmental
format
neat
SMILES string
N.CP(O)(=O)CCC(N)C(O)=O
InChI
1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3
InChI key
ZBMRKNMTMPPMMK-UHFFFAOYSA-N
General description
Glufosinate-ammonium is a phosphinic acid analog of glutamic acid.
Application
Glufosinate-ammonium may be used as a reference standard for the determination of the analyte in:
- Human serum samples by mixed-mode solid-phase extraction (SPE), tert-butyldimethylsilyl (t-BDMS) derivatization and gas chromatography-mass spectrometry (GC-MS) operating on electron impact (EI) mode of detection.
- Water samples by ion-exchange cleanup and derivatization followed by analysis using GC coupled to tandem mass spectrometry (MS/MS) equipped with EI mode of detection.
- Finnish arable soils by high performance liquid chromatography combined with fluorescence detection (HPLC-FLD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Repr. 1B - STOT RE 2
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Determination of glufosinate ammonium and its metabolite, 3-methylphosphinicopropionic acid, in human serum by gas chromatography-mass spectrometry following mixed-mode solid-phase extraction and t-BDMS derivatization.
Hori Y, et al.
Journal of Analytical Toxicology, 25(8), 680-684 (2001)
Ji-Hui Byeon et al.
Biochemical and biophysical research communications, 441(1), 243-248 (2013-10-22)
We present an efficient method for the production of N-acetyl-L-phosphinothricin (N-AcPt) from commercial DL-phosphinothricin (DL-PPT) by organic acetylation for use as a negative selection agent (NSA) that induces cell death in argE transgenic rice. DL-PPT was efficiently converted into N-AcPt
Miao Wang et al.
PloS one, 10(3), e0118476-e0118476 (2015-03-04)
The onset of floral development is a pivotal switch in the life of soybean. Brassinosteroids (BRs), a group of steroidal phytohormones with essential roles in plant growth and development, are associated with flowering induction. Genes involved in BR biosynthesis have

