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Merck

346144

Diethyl ether

≥98%, reagent grade, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

Synonym(s):

Et2O, Ethoxyethane, Ether, Ethyl ether

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About This Item

Linear Formula:
(CH3CH2)2O
CAS Number:
60-29-7
Molecular Weight:
74.12
NACRES:
NA.07
PubChem Substance ID:
329755043
UNSPSC Code:
12352112
EC Number:
200-467-2
MDL number:
MFCD00011646
Beilstein/REAXYS Number:
1696894
grade:
reagent grade
assay:
≥98%
bp:
34.6 °C (lit.)
vapor pressure:
28.5 psi ( 55 °C)
8.38 psi ( 20 °C)

Product Name

Diethyl ether, reagent grade, ≥98%, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

SMILES string

CCOCC

grade

reagent grade

vapor density

2.6 (vs air)

vapor pressure

28.5 psi ( 55 °C)
8.38 psi ( 20 °C)

assay

≥98%

form

liquid

autoignition temp.

320 °F
356 °F

contains

≤2% ethanol and ≤10ppm BHT as inhibitor

expl. lim.

36.5 %

dilution

(for analytical testing)

impurities

≤0.5% (water)

refractive index

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

density

0.706 g/mL at 25 °C (lit.)

Quality Level

100

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General description

Diethylether, also known as ethyl ether or ether, is frequently used as a laboratory solvent. It is highly volatile, non-flammable, has limited solubility in water, and has high solubility in oil. Ethers are favored solvents for oils, fats, waxes, perfumes, dyes, resins, gums, and hydrocarbons. Additionally, it can be used as a fuel and to synthesize other chemical compounds. It is also employed as a solvent for Grignard synthesis.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019,EUH066

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT3248
SHBS9166
SHBS0984
SHBQ4844
SHBM7159

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Oxidation mechanism of diethyl ether: a complex process for a simple molecule
Di Tommaso S, et al.
Physical Chemistry Chemical Physics, 13(32), 14636-14645 (2011)
The grignard reagents
Seyferth D
Organometallics, 28(6), 1598-1605 (2009)
A review on the advancement of ether synthesis from organic solvent to water
Mandal S, et al.
Royal Society of Chemistry Advances, 6(73), 69605-69614 (2016)
The potency of hydrothermally prepared sulfated silica (SO4/SiO2) as a heterogeneous acid catalyst for ethanol dehydration into diethyl ether
Pratika RA, et al.
Chemosphere, 341, 139822-139822 (2023)
Tatsuya Yoshino et al.
Organic letters, 14(16), 4290-4292 (2012-08-09)
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.
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