Silver trifluoromethanesulfonate

Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This catalyst activates carbon-carbon multiple bonds for cycloisomerization with remarkable chemoselectivity. Its compatibility with various functional groups enables mild transformations in pharmaceutical synthesis. Click here for more information.

Silver trifluoromethanesulfonate (AgOTf) may be employed as a reagent during glucosylation of several alcohols. AgOTf in combination with p-nitrobenzenesulfenyl chloride may be employed as an activator for the glycosylation.
It may be used for the synthesis of the following:

• cystine-containing peptides
• 3-aminoalkylated indoles
• benzo[b]oxepines and 2H-chromenes
• diversely substituted iminoimidazoazines

Reagent for the substitution of halides by triflate.; Reagent for the glycosylation of glycosyl halides; Reagent used for the deprotection of protected thiols