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366374

Zinc chloride solution

0.5 M in THF

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
NACRES:
NA.55
PubChem Substance ID:
329755428
UNSPSC Code:
12352302
MDL number:
MFCD00011295
form:
liquid

Product Name

Zinc chloride solution, 0.5 M in THF

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

SMILES string

Cl[Zn]Cl

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

form

liquid

concentration

0.5 M in THF
470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

Quality Level

100

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Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL9069
SHBH1037V
SHBD0457V
SHBC1890V
SHBB8411V

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    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. Why does the MSDS for Product 366374 - 0.5M Zinc Chloride solution in THF state the prdouct may form explosive peroxides?

    Zinc Chloride is not a peroxide former itself but since its mixed with THF, THF is a peroxide former.

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    Ask a Scientist here.

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Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
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