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About This Item
Linear Formula:
CH3CH=CH2
CAS Number:
Molecular Weight:
42.08
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-062-1
Beilstein/REAXYS Number:
1696878
MDL number:
Assay:
≥99%
InChI key
QQONPFPTGQHPMA-UHFFFAOYSA-N
InChI
1S/C3H6/c1-3-2/h3H,1H2,2H3
SMILES string
CC=C
vapor density
1.48 (vs air)
vapor pressure
15.4 atm ( 37.7 °C)
assay
≥99%
autoignition temp.
860 °F
expl. lim.
11.1 %
bp
−47.7 °C (lit.)
mp
−185 °C (lit.)
Quality Level
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General description
Propylene is a nonpolar olefin. It is commonly used as a precursor for the synthesis of cumene, propylene oxide,acrylonitrile, and isopropanol. Selective oxidation of propylene in a gas containing oxygen and hydrogen over Au/TiO2 catalysts has been reported. Polymerization of propylene using Ziegler-Natta catalyst has been studied. Metal-catalyzed copolymerizations of nonpolar olefins (ethylene and propylene) with alkyl acrylates has been described. Copolymerization of propylene with the linear α-olefins 1-octene, 1-decene, 1-tetradecene, and 1-octadecene has been studied.
Application
Propylene may be used in the synthesis of propylene oxide via epoxidation with hydrogen peroxide, in the presence of titanium silicalite catalyst.
Packaging
Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
pcodes
Hazard Classifications
Flam. Gas 1 - Press. Gas Liquefied gas
Storage Class
2A - Gases
wgk
WGK 3
flash_point_f
-162.4 °F - closed cup
flash_point_c
-108 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
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Christian Schäfer et al.
Organic & biomolecular chemistry, 10(16), 3253-3257 (2012-03-13)
Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (η(2)-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly fused unsaturated tricyclic lactones which represent relevant substructures of numerous bioactive compounds.
Thomas Hampel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(33), 10382-10392 (2012-07-19)
The title compounds were synthesized in a longest sequence of 27 linear steps and with an overall yield of 2.9 and 3.9%. In the course of the synthesis, two aldehydes representing carbon fragments C1-C7 (Eastern fragment) and C9-C21 (Western fragment)
Mallory L Hammock et al.
ACS nano, 6(4), 3100-3108 (2012-03-09)
The use of organic transistors as sensing platforms provides a number of distinct advantages over conventional detection technologies, including their tunability, portability, and ability to directly transduce binding events without tedious and expensive labeling procedures. However, detection efforts using organic
The copolymerization of propylene with higher, linear a-olefins.
Van Reenen AJ, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(22), 4110-4118 (2000)
Stefan Wuttke et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(38), 11959-11967 (2012-08-15)
A reducible MIL-100(Fe) metal-organic framework (MOF) was investigated for the separation of a propane/propene mixture. An operando methodology was applied (for the first time in the case of a MOF) in order to shed light on the separation mechanism. Breakthrough
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