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About This Item
Linear Formula:
C6H5SNa
CAS Number:
Molecular Weight:
132.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-224-0
Beilstein/REAXYS Number:
3597302
MDL number:
Assay:
90%
Form:
powder
grade
technical grade
Quality Segment
assay
90%
form
powder
mp
>300 °C (lit.)
SMILES string
[Na]Sc1ccccc1
InChI
1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key
RZWQDAUIUBVCDD-UHFFFAOYSA-M
General description
Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether.
Application
Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:
- As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
- Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
- Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
- Synthesis of Et4N+ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)6]2-.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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