B56501
4-Bromoanisole
≥99.0%
Synonym(s):
1-Bromo-4-methoxybenzene
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About This Item
Linear Formula:
BrC6H4OCH3
CAS Number:
Molecular Weight:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-252-1
Beilstein/REAXYS Number:
1237590
MDL number:
Assay:
≥99.0%
Form:
liquid
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
SMILES string
COc1ccc(Br)cc1
assay
≥99.0%
form
liquid
refractive index
n20/D 1.564 (lit.)
bp
223 °C (lit.)
mp
9-10 °C (lit.)
density
1.494 g/mL at 25 °C (lit.)
Quality Level
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Application
4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.
General description
4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
201.2 °F
flash_point_c
94 °C
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrations than HOBr. The
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Hypobromous acid (HOBr) is an inorganic acid produced by the oxidation of the bromide anion (Br(-)). The blood plasma level of Br(-) is more than 1,000-fold lower than that of chloride anion (Cl(-)). Consequently, the endogenous production of HOBr is
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