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Merck

07-5990

2,2′-Dipyridyl

JIS special grade, ≥99.0%

Synonym(s):

2,2′-Bipyridyl, 2,2′-Bipyridine, 2,2′-Dipyridine, 2,2′-Dipyridyl

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About This Item

Empirical Formula (Hill Notation):
C10H8N2
CAS Number:
366-18-7
Molecular Weight:
156.18
EC Number:
206-674-4
UNSPSC Code:
12352100
PubChem Substance ID:
329748486
Beilstein/REAXYS Number:
113089
MDL number:
MFCD00006212

Key Documents

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InChI key

ROFVEXUMMXZLPA-UHFFFAOYSA-N

InChI

1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H

SMILES string

c1ccc(nc1)-c2ccccn2

grade

JIS special grade

assay

≥99.0%

availability

available only in Japan

bp

273 °C (lit.)

mp

70-73 °C (lit.)

Biochem/physiol Actions

Metalloprotease inhibitor, high-affinity chelator of iron; may inhibit Fe2+ containing enzymes at 10−8 M.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

267.8 °F - closed cup

flash_point_c

131 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
U7551
U5247
U1071
U9070
U2796

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Ralf Haiges et al.
Angewandte Chemie (International ed. in English), 54(31), 9101-9105 (2015-06-16)
Vanadium(V) oxoazide [VO(N3)3] was prepared through a fluoride-azide exchange reaction between [VOF3] and Me3SiN3 in acetonitrile solution. When the highly impact- and friction-sensitive compound [VO(N3)3] was reacted with 2,2′-bipyridine, the adduct [(bipy)VO(N3)3] was isolated. The reaction of [VO(N3)3] with [PPh4]N3
Metal-locked DNA three-way junction.
Jean-Louis H A Duprey et al.
Angewandte Chemie (International ed. in English), 52(4), 1212-1216 (2012-12-15)
Amanda C Bowman et al.
Inorganic chemistry, 52(4), 2242-2256 (2013-02-08)
The electronic structures of the complexes [M((t)bpy)(3)](0,1-) (M = Nb, Ta; (t)bpy = 4,4'-di-tert-butyl-2,2'-bipyridine) have been investigated using a combination of UV-vis spectroscopy, EPR spectroscopy, and XAS. Furthermore, the crystal structure of [Na(THF)(5)][Ta((t)bpy)(3)] has been determined. These studies were supplemented
Hana Krysova et al.
Chimia, 67(3), 149-154 (2013-04-12)
Titania nanofibers were fabricated using the industrial Nanospider(TM) technology. The preparative protocol was optimized by screening various precursor materials to get pure anatase nanofibers. Composite films were prepared by mixing a commercial paste of nanocrystalline anatase particles with the electrospun
Xiang Chen et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4386-4397 (2013-02-13)
Two ruthenium(II) polypyridyl complexes, [Ru(bpy)(2)(ptpn)](2+) (1) (bpy = 2,2'-bipyridine, ptpn = 3-(1,10-phenanthroline-2-yl)-as-triazino[5,6-f]1,10-phenanthroline) and [Ru(phen)(2)(ptpn)](2+) (2) (phen = 1,10-phenanthroline), were synthesized and characterized. Crystal structure analysis shows that complex 1 has a large planar aromatic area and possesses the potential to
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