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Merck

236071

N,N′-Bis(salicylidene)ethylenediamine

98%

Synonym(s):

2,2′-Ethylenebis(nitrilomethylidene)diphenol, N,N′-Ethylenebis(salicylimine)

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About This Item

Linear Formula:
(CH2N=CHC6H4OH)2
CAS Number:
94-93-9
Molecular Weight:
268.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854136
EC Number:
202-376-3
Beilstein/REAXYS Number:
535296
MDL number:
MFCD00002244
Assay:
98%

Key Documents

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InChI key

VEUMANXWQDHAJV-JYFOCSDGSA-N

InChI

1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+

SMILES string

Oc1ccccc1\C=N\CC\N=C\c2ccccc2O

assay

98%

mp

127-128 °C (lit.)

solubility

water: insoluble(lit.)

functional group

amine, imine

Quality Level

100

Related Categories

General description

N,N′-Bis(salicylidene)ethylenediamine (salen) reacts with ferric chloride in acetone solution to yield the complex (Fe salen Cl).

Application

N,N′-Bis(salicylidene)ethylenediamine (salen) immobilized on surfactant-coated alumina has been used as complexing agent for on-line preconcentration of copper and lead by flow injection-flame atomic absorption spectrometry (FI-AAS).

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN9162
MKCF8752
MKBV5297V
MKBQ5356V
MKBL5405V

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Hydration of epoxides on [CoIII salen)] encapsulated in silica-based nanoreactors.
Bo Li et al.
Angewandte Chemie (International ed. in English), 51(46), 11517-11521 (2012-10-16)
Li Zhou et al.
Analytica chimica acta, 735, 96-106 (2012-06-21)
A series of water-soluble sulfonato-Salen-type ligands derived from different diamines including 1,2-ethylenediamine (Et-1-Et-4), 1,2-cyclohexanediamine (Cy-1 and Cy-2), 1,2-phenylenediamine (Ph-1-Ph-3 and PhMe-1-PhMe-4), and dicyano-1,2-ethenediamine (CN-1) has been designed and prepared. Sulfonate groups of ligands ensure good stability and solubility in water
Lakshmi Kanta Das et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 11009-11017 (2012-08-04)
Two new trinuclear hetero-metallic copper(II)-zinc(II) complexes [(CuL)(2)Zn(N(3))(2)] (1A and 1B) have been synthesized using [CuL] as a so-called "metalloligand" (where H(2)L = N,N'-bis(salicylidene)-1,3-propanediamine) and structurally characterized. Complexes 1A and 1B have the same molecular formula but crystallize in different crystal
Erin E Podlesny et al.
Organic letters, 14(18), 4862-4865 (2012-09-04)
The selective oxidation of a series of functionalized 8,8'-hydroxylated binaphthols to binaphtho-para- and binaphtho-ortho-quinones has been realized using either a Co-salen catalyst or ortho-iodoxybenzoic acid. A unique spirocyclic bis-spironaphthalenone was also obtained in good yield via a phenyliodonium diacetate promoted
Immobilized salen (N,N'-bis (salicylidene) ethylenediamine) as a complexing agent for on-line sorbent extraction/preconcentration and flow injection-flame atomic absorption spectrometry.
Dadfarnia S, et al.
Analytica Chimica Acta, 539(1), 69-75 (2005)
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