333239
Titanium(IV) fluoride
powder and chunks
Synonyme(s) :
Titanium tetrafluoride, Titanium fluoride
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A propos de cet article
Formule linéaire :
TiF4
Numéro CAS:
Poids moléculaire :
123.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-017-6
MDL number:
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Titanium(IV) fluoride,
form
powder and chunks
Quality Level
reaction suitability
core: titanium, reagent type: catalyst
density
2.798 g/mL at 25 °C (lit.)
SMILES string
F[Ti](F)(F)F
InChI
1S/4FH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XROWMBWRMNHXMF-UHFFFAOYSA-J
Application
Catalyst for:
- Chemoselective synthesis and deprotection of geminal diacetates of aldehydes
Used for preparation of glycosyl fluorides; glycosylation; preparation of fluorohydrins; addition of carbanions to aldehydes and imines.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Classe de stockage
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Annette Wiegand et al.
Archives of oral biology, 54(8), 790-795 (2009-06-02)
This study aimed to analyse and compare the protective effect of buffered (pH 3.5) and native (pH 1.2) TiF(4) in comparison to NaF solutions of same pH on dentin erosion. Bovine samples were pretreated with 1.50% TiF(4) or 2.02% NaF
Annette Wiegand et al.
Archives of oral biology, 55(3), 223-228 (2010-01-20)
This in situ study aimed to analyse the impact of different tetrafluorides (TiF(4), ZrF(4) and HfF(4)) and AmF on erosion and erosion plus abrasion of enamel and dentin. Ten volunteers took part in this crossover and double-blind study performed in
Thomas R Gordon et al.
Journal of the American Chemical Society, 134(15), 6751-6761 (2012-03-27)
Control over faceting in nanocrystals (NCs) is pivotal for many applications, but most notably when investigating catalytic reactions which occur on the surfaces of nanostructures. Anatase titanium dioxide (TiO(2)) is one of the most studied photocatalysts, but the shape dependence