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Merck

391085

Éthylènediamine

purified by redistillation, ≥99.5%

Synonyme(s) :

1,2-diaminoéthane

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About This Item

Formule linéaire :
NH2CH2CH2NH2
Numéro CAS:
Poids moléculaire :
60.10
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39030201
UNSPSC Code:
12352100
EC Number:
203-468-6
MDL number:
Beilstein/REAXYS Number:
605263
assay:
≥99.5%
bp:
118 °C (lit.)
vapor pressure:
10 mmHg ( 20 °C)

Nom du produit

Éthylènediamine, purified by redistillation, ≥99.5%

InChI key

PIICEJLVQHRZGT-UHFFFAOYSA-N

InChI

1S/C2H8N2/c3-1-2-4/h1-4H2

SMILES string

NCCN

vapor density

2.07 (vs air)

vapor pressure

10 mmHg ( 20 °C)

assay

≥99.5%

form

liquid

autoignition temp.

716 °F

purified by

redistillation

expl. lim.

16 %

refractive index

n20/D 1.4565 (lit.)

pH

12.2 (20 °C, 110 g/L)

bp

118 °C (lit.)

mp

8.5 °C (lit.)

solubility

ethanol: soluble(lit.)
water: miscible(lit.)
water: very soluble(lit.)

density

0.899 g/mL at 25 °C (lit.)

functional group

amine

Quality Level

Gene Information

human ... FNTA(2339)

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Application

Ethylenediamine (en) is suitable for use in the synthesis of covalently linked adducts of deoxyribonucleic acid (DNA) oligonucleotides with single-walled carbon nanotubes. It may be used in the following studies:
  • Functionalization of the triazolate-bridged metal-organic framework.
  • As a solvent in the synthesis of ZnS and ZnSe precursors by solvothermal process.
  • As a softening agent for hard wood plant structure.
  • As a reactant in the synthesis of Pd/C-ethylenediamine complex catalyst.
  • As a chelating agent in the synthesis of β-Co(OH)2 nanocrystals.
  • To produce ethylenediamine modified rice hull, used as a sorbent for basic and reactive dyes.
  • Synthesis of ethylenediamine-templated iron arsenates and fluoroarsenates.
  • As a template agent and coordination agent in the synthesis of CdS nanocrystals.
  • As a reagent in the synthesis of imidazolines.

General description

Ethylenediamine (en) is a linear aliphatic diamine. The synthesis of ethylenediamine has been reported. Its effect as an allergen has been investigated. It participates in the synthesis of metal chalcogenides and thiogallates.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Resp. Sens. 1B - Skin Corr. 1B - Skin Sens. 1B

Classe de stockage

3 - Flammable liquids

wgk

WGK 1

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Consulter la Bibliothèque de documents

Covalently bonded adducts of deoxyribonucleic acid (DNA) oligonucleotides with single-wall carbon nanotubes: synthesis and hybridization.
Baker SE, et al.
Nano Letters, 2(12), 1413-1417 (2002)
Reactions of some ortho and para halogenated aromatic nitriles with ethylenediamine: selective synthesis of imidazolines.
Crane LJ, et al.
Tetrahedron, 60(25), 5325-5330 (2004)
Aude Demessence et al.
Journal of the American Chemical Society, 131(25), 8784-8786 (2009-06-10)
Reaction of CuCl(2) x 2 H(2)O with 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene (H(3)BTTri) in DMF at 100 degrees C generates the metal-organic framework H(3)[(Cu(4)Cl)(3)(BTTri)(8)(DMF)(12)] x 7 DMF x 76 H(2)O (1-DMF). The sodalite-type structure of the framework consists of BTTri(3-)-linked [Cu(4)Cl](7+) square clusters in
S T Ong et al.
Bioresource technology, 98(15), 2792-2799 (2007-04-03)
Wastewaters from textile industries may contain a variety of dyes that have to be removed before their discharge into waterways. Rice hull, an agricultural by-product, was modified using ethylenediamine to introduce active sites on its surface to enable it to
The use of ethylenediamine in softening hard plant structures for paraffin sectioning.
Carlquist, S.
Biotechnic & Histochemistry, 57(5), 311-317 (1982)

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