8.21166
Trifluoromethanesulfonic acid
for synthesis
Synonyme(s) :
Trifluoromethanesulfonic acid, Triflic acid, TFMS
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A propos de cet article
grade
synthesis grade
Quality Level
vapor pressure
10 hPa ( 55 °C)
form
liquid
potency
1605 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rat)
pH
<1 ( in H2O)
bp
162 °C/1013 hPa
density
1.71 g/cm3 at 20 °C
storage temp.
2-30°C
SMILES string
[Ba+2].FC(F)(F)[S](=O)(=O)[O-].FC(F)(F)[S](=O)(=O)[O-]
InChI
1S/2CHF3O3S.Ba/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChI key
DXJURUJRANOYMX-UHFFFAOYSA-L
General description
Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Boc SPPS
Literature references:
[1] L. R. Subramanian, et al. (2001) Encyclopedia of Reagents for Organic Synthesis.
[2] R. D. Howells & J. D. Mc Cown JD (1977) Chem. Rev., 77, 69.
[3] J. Stewart, J. Young in “Solid Phase Peptide Synthesis”, Pierce Chemical Company, Rockford, 1984.
Application
- A dehydrating agent for the conversion of secondary alcohols to alkene, or the preparation of anhydrides from carboxylic acids.
- An acid catalyst in the synthesis of carbohydrates and glycosides.
- An activating agent for the activation of carboxylic acids and can be used for the synthesis of carboxylic acid derivatives such as esters, amides, and anhydrides.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Classe de stockage
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
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