289329
Cesium chloride
ReagentPlus®, 99.9%
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A propos de cet article
Formule linéaire :
CsCl
Numéro CAS:
Poids moléculaire :
168.36
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-600-2
MDL number:
Assay:
99.9%
Form:
crystals, chunks or beads
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product line
ReagentPlus®
assay
99.9%
form
crystals, chunks or beads
pH
6-7.5
mp
645 °C (lit.)
SMILES string
[Cl-].[Cs+]
InChI
1S/ClH.Cs/h1H;/q;+1/p-1
InChI key
AIYUHDOJVYHVIT-UHFFFAOYSA-M
Application
Cesium chloride can be used as:
- A reagent to synthesize macrocyclic tetralactones via ring-closing metathesis reaction of diolefins in the presence of Grubbs catalyst.
- An additive in the palladium-catalyzed selective carbonylative coupling of less reactive aryl chlorides with primary and secondary aliphatic and aromatic amines to synthesize aromatic amides.
- An activator for low-valent titanium reagents that can be used in the reductive coupling of acetophenone.
Other Notes
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
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Warning
hcodes
Hazard Classifications
Repr. 2
Classe de stockage
13 - Non Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
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F F White et al.
Journal of bacteriology, 164(1), 33-44 (1985-10-01)
The T-DNA regions of the root-inducing (Ri) plasmid pRiA4b of Agrobacterium rhizogenes were characterized. Two regions, designated TL-DNA and TR-DNA, were found to be integrated and stably maintained in the plant genome. The TL-DNA spanned a 15- to 20-kilobase region
Ribonucleic acid isolated by cesium chloride centrifugation.
Glisin V, et al.
Biochemistry, 13(12), 2633-2637 (1974)
Eagleson M.
Concise Encyclopedia Chemistry, 198-198 (1994)