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Merck

32201

Acétone

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (GC)

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A propos de cet article

Formule linéaire :
CH3COCH3
Numéro CAS:
Poids moléculaire :
58.08
NACRES:
NA.02
PubChem Substance ID:
eCl@ss:
39021201
UNSPSC Code:
12352115
EC Number:
200-662-2
MDL number:
Beilstein/REAXYS Number:
635680
Assay:
≥99.5% (GC)
Technique(s):
UV/Vis spectroscopy: suitable
Bp:
56 °C/760 mmHg (lit.)
Vapor pressure:
184 mmHg ( 20 °C)
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Quality Segment

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor density

2 (vs air)

vapor pressure

184 mmHg ( 20 °C)

grade

ACS reagent, puriss. p.a.

assay

≥99.5% (GC)

form

liquid

expl. lim.

13.2 %

technique(s)

UV/Vis spectroscopy: suitable

impurities

≤0.0002% KMnO4 red. matter (as O), ≤0.0002% benzene, ≤0.0008% free alkali (as NH3), ≤0.001% aldehydes (as HCHO), ≤0.001% non-volatile matter, ≤0.0015% free acid (as CH3COOH), ≤0.01% ethanol (GC), ≤0.05% 2-propanol, ≤0.05% methanol, ≤0.2% water (Karl Fischer)

refractive index

n20/D 1.3580-1.3600, n20/D 1.359 (lit.)

pH

5-6 (20 °C, 395 g/L)

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

SMILES string

CC(C)=O

cation traces

Al: ≤0.5 ppm, B: ≤0.02 ppm, Ba: ≤0.1 ppm, Bi: ≤0.1 ppm, Ca: ≤0.5 ppm, Cd: ≤0.05 ppm, Co: ≤0.01 ppm, Cr: ≤0.02 ppm, Cu: ≤0.02 ppm, Fe: ≤0.1 ppm, K: ≤0.5 ppm, Li: ≤0.1 ppm, Mg: ≤0.1 ppm, Mn: ≤0.01 ppm, Mo: ≤0.1 ppm, Na: ≤0.5 ppm, Ni: ≤0.02 ppm, Pb: ≤0.02 ppm, Sn: ≤0.1 ppm, Sr: ≤0.1 ppm, Zn: ≤0.05 ppm

format

neat

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

General description

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C have been reported to efficiently photocatalyze oxidation of acetone. Its aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

Application

Acetone was used in the synthesis of Ga (Gallium)-DOTATATE (where DOTA=1,4,7,10-tetraazacyclo- dodecane -1,4,7,10-tetraacetic acid) chemicals. It may be used in an assay for determination of ester groups in lipids by spectrophotometric methods.
L′intensité de la luminescence de l′acétone dépend des constituants de la solution . L′absorption des rayonnements UV par l′acétone entraîne sa photolyse et la production de radicaux .

Other Notes

The article number 32201-4X2.5L will be discontinued. Please order the single bottle 32201-2.5L which is physically identical with the same exact specifications.
The article number 32201-6X1L will be discontinued. Please order the single bottle 32201-1L which is physically identical with the same exact specifications.
The article number 32201-6X1L-M will be discontinued. Please order the single bottle 32201-1L-M which is physically identical with the same exact specifications.


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Classe de stockage

3 - Flammable liquids

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.0 °C - closed cup



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