13112
Magnesio
powder, ≥99%
Sinónimos:
Magnesium element
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Fórmula empírica (notación de Hill):
Mg
Número CAS:
Peso molecular:
24.31
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
38110201
UNSPSC Code:
12141502
EC Number:
231-104-6
MDL number:
Beilstein/REAXYS Number:
4948473
Assay:
≥99%
Form:
powder
Servicio técnico
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Permítanos ayudarlevapor pressure
1 mmHg ( 621 °C)
Quality Level
assay
≥99%
form
powder
autoignition temp.
950 °F
reaction suitability
reagent type: reductant
resistivity
4.46 μΩ-cm, 20°C
impurities
≤0.05% insoluble in HCl
bp
1090 °C (lit.)
mp
648 °C (lit.)
density
1.74 g/mL at 25 °C (lit.)
cation traces
Fe: ≤500 mg/kg
SMILES string
[Mg]
InChI
1S/Mg
InChI key
FYYHWMGAXLPEAU-UHFFFAOYSA-N
Application
Magnesium (powder) can be used as a reducing agent to synthesize:
It can also be used as a reducing agent in ruthenium(III) complex catalyzed atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions. Magnesium does not generate free radicals but it generates and regenerates the catalytically active ruthenium(II) species.
- Titanium alloy hydride powder by the reduction of upgraded titania slag (UGS) under hydrogen atmosphere.
- Ultrafine metallic iron (bcc-Fe) powders from hematite (α-Fe2O3) by ball-milling process.
It can also be used as a reducing agent in ruthenium(III) complex catalyzed atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions. Magnesium does not generate free radicals but it generates and regenerates the catalytically active ruthenium(II) species.
Analysis Note
appearance : silver-gray
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signalword
Danger
hcodes
Clase de almacenamiento
4.2 - Pyrophoric and self-heating hazardous materials
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Flam. Sol. 1 - Self-heat. 1 - Water-react. 2
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Hyperbranched polyalkenylsilanes by hydrosilylation with platinum catalysts. I. Polymerization
Drohmann C, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(4), 741-751 (2000)
Ultrafine spinel powders by flame spray pyrolysis of a magnesium aluminum double alkoxide.
Bickmore CR, et al.
Journal of the American Chemical Society, 79(5), 1419-1423 (1996)
Katrin Thommes et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(24), 6899-6907 (2007-06-05)
A new catalytic procedure for atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl(2)Cp*(PPh3)] (Cp*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild conditions with high efficiency. In most