243205
Trimethylamine
anhydrous, ≥99%
Sinónimos:
N,N,N-Trimethylamine, N,N-Dimethylmethanamine
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Fórmula lineal:
(CH3)3N
Número CAS:
Peso molecular:
59.11
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-875-0
Beilstein/REAXYS Number:
956566
MDL number:
Assay:
≥99%
Servicio técnico
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anhydrous
Quality Level
vapor density
2.09 (vs air)
vapor pressure
13.3 psi ( 21 °C)
assay
≥99%
autoignition temp.
374 °F
expl. lim.
11.6 %
impurities
≤0.05% ammonia, ≤0.05% methylamine, ≤0.2% dimethylamine
bp
3-4 °C (lit.)
mp
−117 °C (lit.)
density
0.63 g/mL at 20 °C (lit.)
functional group
amine
storage temp.
2-8°C
SMILES string
CN(C)C
InChI
1S/C3H9N/c1-4(2)3/h1-3H3
InChI key
GETQZCLCWQTVFV-UHFFFAOYSA-N
Application
Trimethylamine (TMA) has been used in the preparation of poly[9,9′-bis(6′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), a water-soluble, cationic conjugated polymer used in label-free DNA microarrays. It can also be used to prepare benzyltrimethylammonium chloride, which then reacts with sodium ethoxide to form benzyltrimethylammonium ethoxide. The adsorption of TMA on the gold surface of trimethylsilylated barium nitrate-gold/titanosilicate catalyst acts as a promoter for the propylene epoxidation with oxygen and hydrogen.
Packaging
Supplied in a Sure/Pac™ cylinder and has a 316 stainless steel needle valve with a male 1/4" NPTF outlet thread installed . Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Gas 1A - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Clase de almacenamiento
2A - Gases
wgk
WGK 1
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
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Trimethylamine as a Gas?Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts.
Chowdhury B, et al.
Angewandte Chemie (International Edition in English), 45(3), 412-415 (2006)
Benzyltrimethylammonium Ethoxide: Ammonium, benzyltrimethyl?, ethoxide
Croxall W J, et al.
Organic Syntheses, 38, 5-5 (2003)
Bin Liu et al.
Nature protocols, 1(4), 1698-1702 (2007-05-10)
We describe the synthesis of poly[9,9'-bis(6''-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), a cationic, water-soluble conjugated polymer used in label-free DNA microarrays. This polymer was designed to have a maximum absorbance of close to 488 nm, which meets the excitation wavelength of most commercial