317594
Trimethylamine N-oxide
95%
Sinónimos:
TMANO
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Acerca de este artículo
Fórmula lineal:
(CH3)3N(O)
Número CAS:
Peso molecular:
75.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
214-675-6
MDL number:
Assay:
95%
Servicio técnico
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Permítanos ayudarleQuality Level
assay
95%
reaction suitability
reagent type: oxidant
mp
220-222 °C (lit.)
functional group
amine
SMILES string
C[N+](C)(C)[O-]
InChI
1S/C3H9NO/c1-4(2,3)5/h1-3H3
InChI key
UYPYRKYUKCHHIB-UHFFFAOYSA-N
General description
Trimethylamine N-oxide is an organic compound that belongs to the class of amine oxides. It is generally found in the tissues of marine organisms, wherein it helps protect them from harsh conditions like salinity, hydrostatic pressure, temperature, and high urea.
Application
Trimethylamine N-oxide can be used:
- As a demetallation and decarbonylation reagent for organometallic compounds.
- To prepare azomethine ylide by reaction with lithium di-isopropylamide. This, in turn, may be reacted with simple alkenes to obtain corresponding pyrrolidines.
- To mediate the conversion of thiols to disulfides.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Clase de almacenamiento
11 - Combustible Solids
ppe
dust mask type N95 (US), Eyeshields, Gloves
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J Klysik et al.
FEBS letters, 333(3), 261-267 (1993-11-01)
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Site selectivity studies on heterobimetallic complexes: substitution reactions of (.eta.5-C5H5)MM'(CO)8 (M = Mo, W; M' = Mn, Re)
Ingham WL and Coville NJ
Inorganic Chemistry, 31(20), 4084-4090 (1992)
Hydride ion transfer from carbon-hydrogen bonds to carbon disulfide, carbonyl sulfide, and carbon dioxide. Synthesis, reactivity, and structure of manganese complexes (η 5-C6MenH7-n) Mn (CO) LL'
Snyder DB, et al.
Journal of the American Chemical Society, 115(15), 6718-6729 (1993)