323446
Ammonium tetrathiomolybdate
99.97% trace metals basis
Sinónimos:
Ammonium thiomolybdate, Diammonium tetrathiomolybdate
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Fórmula lineal:
(NH4)2MoS4
Número CAS:
Peso molecular:
260.28
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
99.97% trace metals basis
Form:
crystalline
Servicio técnico
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99.97% trace metals basis
form
crystalline
reaction suitability
reagent type: catalyst
impurities
≤350.0 ppm Trace Metal Analysis
mp
>300 °C (lit.)
SMILES string
[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S
InChI
1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2
InChI key
PQNOIAHNKHBLRN-UHFFFAOYSA-P
Application
This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.
Ring opening of aziridines leading to sulfides and disulfides.
Biochem/physiol Actions
Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.
Clase de almacenamiento
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.