436267
Di-tert-butyl dicarbonate solution
1.0 M in THF
Sinónimos:
Di-tert-butyl pyrocarbonate
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Fórmula lineal:
O[CO2C(CH3)3]2
Número CAS:
Peso molecular:
218.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Servicio técnico
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liquid
Quality Level
concentration
1.0 M in THF
bp
65-67 °C
density
0.913 g/mL at 25 °C
application(s)
peptide synthesis
functional group
carbonate
SMILES string
CC(C)(C)OC(=O)OC(=O)OC(C)(C)C
InChI
1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3
InChI key
DYHSDKLCOJIUFX-UHFFFAOYSA-N
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Clase de almacenamiento
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Organic & biomolecular chemistry, 4(14), 2769-2771 (2006-07-11)
Perchloric acid adsorbed on silica-gel (HClO4-SiO2) was found to be a new, highly efficient, inexpensive and reusable catalyst for chemoselective N-tert-butoxycarbonylation of amines at room temperature and under solvent-free conditions.
Brandon S Fowler et al.
Journal of the American Chemical Society, 132(9), 2870-2871 (2010-02-18)
We report a fundamentally unique approach to the catalytic kinetic resolution of amine derivatives based on formamide and thioformamide substrates. Readily accessible histidine-containing peptides mediate the kinetic resolutions with as little as 5 mol % catalyst. Selectivity factors (k(rel)) as
Jason C Green et al.
Organic letters, 13(20), 5500-5503 (2011-09-21)
Total syntheses of two structures purported as (+)-heliananes were completed in six pots. Spectral comparisons, between the synthetic and natural compounds, revealed a misassignment of the eight-membered ring in the heliananes. The key step in the syntheses of the proposed