164992
Sodium methoxide
reagent grade, 95%, powder
Sinónimos:
Sodium methylate
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Fórmula lineal:
NaOCH3
Número CAS:
Peso molecular:
54.02
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-699-5
Beilstein/REAXYS Number:
3592982
MDL number:
Assay:
95%
Grade:
reagent grade
Form:
powder
Servicio técnico
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reagent grade
Quality Level
vapor density
1.1 (vs air)
vapor pressure
50 mmHg ( 20 °C)
assay
95%
form
powder
autoignition temp.
851 °F
expl. lim.
36 %
SMILES string
[Na+].C[O-]
InChI
1S/CH3O.Na/c1-2;/h1H3;/q-1;+1
InChI key
WQDUMFSSJAZKTM-UHFFFAOYSA-N
General description
Sodium methoxide is a sodium alkoxide. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF to afford arenes.
Application
Sodium methoxide has been used in the preparation of 5-(3-azidopropyl) uridine. It may be used in the synthesis of methyl 2-cyano-lup-3-hydroxy-2-en-28-oate (CN-BA), a 2-cyano derivative of betulinic acid (BA).
Sodium methoxide may be used as an alkali catalyst for the production of fatty acid methyl esters (biodiesel) from vegetable oils via transesterification.
signalword
Danger
hcodes
supp_hazards
Clase de almacenamiento
4.2 - Pyrophoric and self-heating hazardous materials
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Met. Corr. 1 - Self-heat. 1 - Skin Corr. 1A
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Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil.
Rashid U and Anwar F
Fuel: The Science and Technology of Fuel and Energy, 87(3), 265-273 (2008)
A review on biodiesel production using catalyzed transesterification
Leung DYC, et al
Applied Energy, 87(4), 1083-1095 (2010)
Palladium hydrides in organic synthesis. Reduction of aryl halides by sodium methoxide catalyzed by tetrakis (triphenylphosphine) palladium.
Zask A and Helquist P.
The Journal of Organic Chemistry, 43(8), 1619-1620 (1978)