32951
TDCPP
PESTANAL®, analytical standard
Sinónimos:
Phosphorsäure-tris-(1,3-dichlor-2-propylester)
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Fórmula empírica (notación de Hill):
C9H15Cl6O4P
Número CAS:
Peso molecular:
430.90
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
EC Number:
237-159-2
MDL number:
Servicio técnico
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analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
density
1.514 g/mL at 20 °C (lit.)
application(s)
agriculture
environmental
format
neat
SMILES string
ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl
InChI
1S/C9H15Cl6O4P/c10-1-7(2-11)17-20(16,18-8(3-12)4-13)19-9(5-14)6-15/h7-9H,1-6H2
InChI key
ASLWPAWFJZFCKF-UHFFFAOYSA-N
General description
TDCPP is classified under the chlorinated trialkyl organophosphate flame retardant (OPFR) group of compounds primarily utilized as additives in commercial products such as plastics, paints, textiles, furniture, etc.
Application
TDCPP may be used as an analytical reference standard for the determination of the analyte in:
- Eggs by liquid chromatography-tandem quadrupole mass spectrometry (LC-MS/MS).
- Fish samples by gas chromatography-nitrogen-phosphorus detector (GC-NPD), LC-MS/MS and on-line turbulent flow chromatography (TFC) in conjunction with LC-MS/MS.
- Environmental samples by GC-MS/MS.
- Fruits and vegetables by GC-MS/MS and GC coupled with electron capture detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Other Notes
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 1 - Carc. 2
Clase de almacenamiento
10 - Combustible liquids
wgk
WGK 2
flash_point_f
482.0 - 485.6 °F - open cup
flash_point_c
250 - 252 °C - open cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Analysis of organophosphorus flame retardants in environmental and biotic matrices using on-line turbulent flow chromatography-liquid chromatography-tandem mass spectrometry.
Giulivo M, et al.
Journal of Chromatography A, 1474(2), 71-78 (2016)
Sean P McGee et al.
Environmental health perspectives, 120(11), 1585-1591 (2012-09-29)
Chlorinated phosphate esters (CPEs) are widely used as additive flame retardants for low-density polyurethane foams and have frequently been detected at elevated concentrations within indoor environmental media. To begin characterizing the potential toxicity of CPEs on early vertebrate development, we
Determination of organophosphorous flame retardants in fish tissues by matrix solid-phase dispersion and gas chromatography.
Campone L, et al.
Analytical and Bioanalytical Chemistry, 397(2), 799-806 (2010)