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Merck

471216

Diethylamine

≥99.5%, liquid, suitable for GC/MS

Sinónimos:

N,N-Diethylamine, N-ethyl-ethanamine, DEA, Diethamine, Diethyl amine

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Fórmula lineal:
(C2H5)2NH
Número CAS:
Peso molecular:
73.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-716-3
MDL number:
Beilstein/REAXYS Number:
605268
Assay:
≥99.5%
Technique(s):
GC/MS: suitable
Bp:
55 °C (lit.)
Vapor pressure:
14.14 psi ( 55 °C), 180 mmHg ( 20 °C), 3.51 psi ( 20 °C)
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Nombre del producto

Diethylamine, ≥99.5%

vapor density

2.5 (vs air)

Quality Level

vapor pressure

14.14 psi ( 55 °C), 180 mmHg ( 20 °C), 3.51 psi ( 20 °C)

assay

≥99.5%

form

liquid

autoignition temp.

594 °F

expl. lim.

10.1 %

technique(s)

GC/MS: suitable

refractive index

n20/D 1.385 (lit.)

pH

13 (20 °C, 100 g/L)

bp

55 °C (lit.)

mp

−50 °C (lit.)

solubility

water: soluble

density

0.707 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CCNCC

InChI

1S/C4H11N/c1-3-5-4-2/h5H,3-4H2,1-2H3

InChI key

HPNMFZURTQLUMO-UHFFFAOYSA-N

General description

Diethylamine (DEA) is an organic base and a weak σ-donor ligand.

Application

Diethylamine has been used to constitute the extraction solvent mixture for the gas chromatography-mass spectrometric (GC-MS) analysis of melamine and related compounds. It has been also been used as a bond breaking agent in a novel ELISA technique to measure the avidity index (AI) of IgG-anti-PT (Immunoglobulin G-anti-pertussis toxin) antibodies.
It may be used as:
  • An organocatalyst for the preparation of β-phosphonomalononitriles and diethyl (2-amino-3- cyano-chromene-4-yl) phosphonic acid esters.
  • A ligand for the synthesis of (N-heterocyclic carbene)PdCl2(diethylamine) complexes.
  • A template for the preparation of thermally and hydrothermally stable SAPO-34 (silicoaluminophosphate) molecular sieves.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-14.8 °F - closed cup

flash_point_c

-26 °C - closed cup

ppe

Faceshields, Gloves, Goggles



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Synthesis, characterization and catalytic properties of SAPO-34 synthesized using diethylamine as a template.
Liu G, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 111(1), 143-149 (2008)
Inhibited Catalyst Activation in (N-Heterocyclic carbene) PdCl2 (diethylamine) Complexes by Intramolecular Hydrogen Bonding.
Chen MT, et al.
Organometallics, 30(24), 6770-6773 (2011)
Alex-Mikael Barkoff et al.
Vaccine, 30(48), 6897-6902 (2012-09-18)
Pertussis toxin (PT) is a specific virulence factor of Bordetella pertussis and it is included in all acellular pertussis vaccines (aP). Although immunity after infection seems to persist longer than that after vaccination, the exact mechanism(s) is not known. Primary