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Merck

277576

Bromine

ACS reagent, ≥99.5%

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Fórmula lineal:
Br2
Número CAS:
Peso molecular:
159.81
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12141915
EC Number:
231-778-1
MDL number:
Assay:
≥99.5%
Grade:
ACS reagent
Form:
liquid
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grade

ACS reagent

Quality Segment

vapor density

7.14 (vs air)

vapor pressure

175 mmHg ( 20 °C), 671 mmHg ( 55 °C)

assay

≥99.5%

form

liquid

resistivity

7.8E18 μΩ-cm, 20°C

impurities

organic bromine compounds, passes test, ≤0.001% I2, ≤0.001% S compounds

evapn. residue

≤0.005%

bp

58.8 °C (lit.)

mp

−7.2 °C (lit.)

density

3.119 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.05%

cation traces

Ni: ≤5 ppm, heavy metals: ≤2 ppm

SMILES string

BrBr

InChI

1S/Br2/c1-2

InChI key

GDTBXPJZTBHREO-UHFFFAOYSA-N

General description

Bromine is a highly volatile and reactive halogen that can be used as a powerful brominating and oxidizing agent in chemical synthesis.

Application

Bromine can be used as a brominating agent for the bromination of:
  • Aromatic and heterocyclic compounds. 
  • Carbonyl compounds at α position to carbonyl groups.
  • Aromatic carboxylic acids via Hell-Volhard-Zelinski reaction in the presence of phosphorus trihalides.
  • Alkylbenzenes at the benzylic position using photocatalytic conditions.

It can also be used as an oxidizing agent for the oxidation of:
  • Primary alcohols to either aldehydes or esters.      
  • Secondary alcohols to ketones.

It can also be used as a Lewis acid catalyst to:     
  • Convert epoxides and CO2 to cyclic carbonates in a continuous flow system.     
  • Synthesize bis(indolyl)methanes by reacting indoles with carbonyl compounds.



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Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A

Clase de almacenamiento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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