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Merck

254223

Iron(III) nitrate nonahydrate

greener alternative

≥99.95% trace metals basis, crystals

Synonym(s):

Ferric nitrate nonahydrate

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About This Item

Linear Formula:
Fe(NO3)3 · 9H2O
CAS Number:
Molecular Weight:
404.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-899-5
MDL number:
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Product Name

Iron(III) nitrate nonahydrate, ≥99.95% trace metals basis

Quality Level

assay

≥99.95% trace metals basis

form

crystals

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

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mp

47 °C (lit.)

greener alternative category

SMILES string

O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Fe.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;

InChI key

SZQUEWJRBJDHSM-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

A variety of organically templated iron phosphates, of interest because of their rich crystal chemistry and their ability to absorb large molecules in their micropores,were prepared using this compound.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Lii, K-H. et al.
Chemistry of Materials, 10, 2599-2599 (1998)
Todd C Harrop et al.
Inorganic chemistry, 44(20), 6918-6920 (2005-09-27)
Reaction of excess NO with the S = 3/2 Fe(III) complex (Et4N)2[Fe(PhPepS)(Cl)] (1) in protic solvents such as MeOH affords the {Fe-NO}(7) nitrosyl (Et(4)N)(2)[Fe(PhPepS)(NO)] (2). This distorted square-pyramidal S = 1/2 complex, a product of reductive nitrosylation, is the first
Sangchul Hwang et al.
Chemosphere, 78(5), 563-568 (2009-12-05)
Fenton-driven oxidation of methyl tert-butyl ether (MTBE) (0.11-0.16mM) in batch reactors containing ferric iron (5mM) and hydrogen peroxide (H(2)O(2)) (6mM) (pH=3) was performed to investigate MTBE transformation mechanisms. Independent variables included the forms of iron (Fe) (Fe(2)(SO(4))(3).9H(2)O and Fe(NO(3))(3).9H(2)O), H(2)O(2)
Youshan Sun et al.
Bioresource technology, 102(3), 2936-2942 (2010-12-15)
Five inorganic salts, ZnCl(2), FeSO(4), Fe(2)(SO(4))(3), FeCl(3) and Fe(NO(3))(3) were chosen as catalysts to determine their effects on hemicellulose hydrolysis in control silage (no silage additive), and the results indicated that Fe(NO(3))(3) was the most efficient catalyst for hemicellulose hydrolysis.
Etching and dimerization: a simple and versatile route to dimers of silver nanospheres with a range of sizes.
Weiyang Li et al.
Angewandte Chemie (International ed. in English), 49(1), 164-168 (2009-11-28)

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