118303
1,9-Decadiene
97%
Synonym(s):
Deca-1,9-diene
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About This Item
Linear Formula:
CH2=CH(CH2)6CH=CH2
CAS Number:
Molecular Weight:
138.25
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39010313
UNSPSC Code:
12352100
EC Number:
216-711-6
MDL number:
Beilstein/REAXYS Number:
1697870
Assay:
97%
InChI key
NLDGJRWPPOSWLC-UHFFFAOYSA-N
InChI
1S/C10H18/c1-3-5-7-9-10-8-6-4-2/h3-4H,1-2,5-10H2
SMILES string
C=CCCCCCCC=C
assay
97%
Quality Level
refractive index
n20/D 1.432 (lit.)
bp
169 °C (lit.)
density
0.75 g/mL at 25 °C (lit.)
functional group
allyl
Related Categories
General description
1,9-Decadiene acts as comonomer and undergoes acyclic diene metathesis (ADMET) copolymerization with 1, 5-hexadiene to form random linear polybutadiene –polyoctenamer copolymers. It undergoes ADMET copolymerization with divinyltetraethoxydisiloxane to yield siloxylene–vinylene–alkenylene copolymer.
Application
1,9-Decadiene was used in synthesis and characterization of new telechelic polyoctenamers prepared by ADMET polymerization using Grubbs catalyst.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Brent L Lee et al.
The Journal of chemical physics, 144(24), 245103-245103 (2016-07-03)
The time-resolved parallel artificial membrane permeability assay with fluorescence detection and comprehensive computer simulations are used to study the passive permeation of three aromatic dipeptides-N-acetyl-phenylalanineamide (NAFA), N-acetyltyrosineamide (NAYA), and N-acetyl-tryptophanamide (NATA) through a 1,2-dioleoyl-sn-glycero-3-phospocholine (DOPC) lipid bilayer. Measured permeation times
Acyclic diene metathesis copolymerization of 1, 5-hexadiene and 1, 9-decadiene.
Wagener KB, et al.
Macromolecules, 23(24), 5155-5157 (1990)
ADMET copolymerization of divinyltetraethoxydisiloxane with 1, 9-decadiene catalyzed by Grubbs' catalyst.
Malecka E, et al.
J. Mol. Catal. A: Chem., 190(1), 27-31 (2002)
Synthesis of ABA triblock copolymers via acyclic diene metathesis polymerization and living polymerization of a-amino acid-N-carboxyanhydrides.
Brzezinska KR and Deming TJ.
Macromolecules, 34(13), 4348-4354 (2001)
Shuzhe Wang et al.
Journal of medicinal chemistry, 64(17), 12761-12773 (2021-08-19)
Cyclic peptides have received increasing attention over the recent years as potential therapeutics for "undruggable" targets. One major obstacle is, however, their often relatively poor bioavailability. Here, we investigate the structure-permeability relationship of 24 cyclic decapeptides that share the same
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