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Merck

241288

Triphenyl phosphate

≥99%

Synonym(s):

Triphenoxyphosphine oxide

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About This Item

Linear Formula:
(C6H5O)3PO
CAS Number:
115-86-6
Molecular Weight:
326.28
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854472
EC Number:
204-112-2
Beilstein/REAXYS Number:
1888236
MDL number:
MFCD00003031
Assay:
≥99%

Key Documents

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Product Name

Triphenyl phosphate, ≥99%

InChI key

XZZNDPSIHUTMOC-UHFFFAOYSA-N

InChI

1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H

SMILES string

O=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3

vapor pressure

1.3 mmHg ( 200 °C)

assay

≥99%

bp

244 °C/10 mmHg (lit.)

mp

48-50 °C (lit.)

solubility

acetone: soluble(lit.)
alcohol: moderately soluble(lit.)
benzene: soluble(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)
water: insoluble(lit.)

functional group

phosphate

Quality Level

200

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Application

Triphenyl phosphate was used as an internal standard in the screening and quantification of pesticide residues in vegetables and fruits.

General description

Triphenyl phosphate, an organophosphorus flame retardant (PFR), was determined in human milk sample.

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

428.0 °F - closed cup

flash_point_c

220 °C - closed cup

ppe

Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0435
BCCN2435
BCCN2434
BCCM0928
BCCM4780

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Joon-Woo Kim et al.
Chemosphere, 116, 91-97 (2014-03-19)
In this study, the concentrations of 10 organophosphorus flame retardants (PFRs) were determined in 89 human breast milk samples collected from Japan, the Philippines and Vietnam. Among the targeted PFRs, tris(2-chloroexyl) phosphate (TCEP) and triphenyl phosphate (TPHP) were the predominant
Rainer Hoenicke et al.
Environmental research, 105(1), 132-144 (2007-03-06)
While over seven million organic and inorganic compounds that have been indexed by the American Chemical Society's Chemical Abstracts Service in their CAS Registry are commercially available, most pollution monitoring programs focus only on those chemical stressors for which regulatory
Amer El-Batta et al.
The Journal of organic chemistry, 72(14), 5244-5259 (2007-06-15)
Water is demonstrated to be an effective medium for the Wittig reaction over a wide range of stabilized ylides and aldehydes. Despite sometimes poor solubility of the reactants, good chemical yields normally ranging from 80 to 98% and high E-selectivities
Chunsheng Liu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 147-157 (2013-01-12)
Tris(1,3-dichloro-2-propyl) phosphate (TDCPP) and triphenyl phosphate (TPP) are frequently detected in biota, including fish. However, knowledge of the toxicological and molecular effects of these currently used flame retardants is limited. In the present study, an in vivo screening approach was
Nele Van den Eede et al.
Talanta, 89, 292-300 (2012-01-31)
A new method was optimized for the simultaneous determination of several flame retardants (FRs) in indoor dust, namely polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDs), novel brominated flame retardants (NBFRs) and organophosphate ester flame retardants (OPFRs). The method was based on
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