326712
Ruthenium black
Synonym(s):
Ruthenium
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About This Item
Empirical Formula (Hill Notation):
Ru
CAS Number:
Molecular Weight:
101.07
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141739
EC Number:
231-127-1
MDL number:
assay
≥98%
Quality Level
form
powder
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
resistivity
7.1 μΩ-cm, 0°C
surface area
17-26 m2/g
bp
3900 °C (lit.)
mp
2310 °C (lit.)
density
12.45 g/cm3 (lit.)
greener alternative category
, Enabling
SMILES string
[Ru]
InChI
1S/Ru
InChI key
KJTLSVCANCCWHF-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Application
Ru based complexes may be used in the synthesis of anticancer drugs. Ru complexes in conjunction with magnesium may be used in the atom transfer radical addition (ATRA) and cyclization (ATRC) reactions.
Ru may be used as a catalyst in the following reactions;
Ru may be used as a catalyst in the following reactions;
- oxidative coupling of indoles and pyrroles with several alkenes
- arylations reactions.
Packaging
Packaged in glass bottles
Storage Class
4.1B - Flammable solid hazardous materials
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and
M Beye et al.
Physical review letters, 110(18), 186101-186101 (2013-05-21)
We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et
Rafael E Rodríguez-Lugo et al.
Nature chemistry, 5(4), 342-347 (2013-03-21)
The development of an efficient catalytic process that mimics the enzymatic function of alcohol dehydrogenase is critical for using biomass alcohols for both the production of H2 as a chemical energy carrier and fine chemicals under waste-free conditions. Dehydrogenation of