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Merck

86040

Sulfamic acid

analytical standard (for acidimetry), ACS reagent

Synonym(s):

Aminosulfonic acid, Sulphamic acid, Amidosulfonic acid

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About This Item

Linear Formula:
NH2SO3H
CAS Number:
5329-14-6
Molecular Weight:
97.09
EC Number:
226-218-8
MDL number:
MFCD00011603
NACRES:
NA.25
PubChem Substance ID:
329769435
UNSPSC Code:
12161700

Key Documents

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InChI key

IIACRCGMVDHOTQ-UHFFFAOYSA-N

InChI

1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)

grade

ACS reagent, analytical standard (for acidimetry)

agency

complies with DIN 19266

assay

99.3-100.3% (dried material)

mp

215-225 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg, sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤10 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

application(s)

environmental
food and beverages
general analytical
industrial qc
pharmaceutical

format

mixture

Quality Level

100

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General description

Sulfamic acid, a strong inorganic acid, exists in crystalline form. It is stable, non-hygroscopic, odorless, and colorless in dry state, making its commercial packaging and handling convenient.

Application

It can be used as an acidimetric standard for analytical applications.
Sulfamic acid also finds its use as a primary standard in non-aqueous visual, conductometric, and potentiometric titrations.

Features and Benefits

  • Available in a secure glass bottle to ensure its stability for the entire shelf life until opened.
  • High-quality offering accurate titer determinations
  • Accompanied by a detailed certificate of analysis (CoA)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0139
BCCM5328
BCCL2006
BCCM3324
BCCK1487

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Na Zhang et al.
The Journal of organic chemistry, 77(14), 5956-5964 (2012-06-21)
The efficiency of arylboron-based nucleophiles, boronic acid, potassium trifluoroborate, neopentylglycolboronate, and pinacol boronate in nickel-catalyzed Suzuki-Miyaura cross-coupling reactions with the two C-O electrophiles, mesylates, and sulfamates was compared. Arylboronic acid is the most reactive and most atom-economic of the four
Amit Saha et al.
Chemical communications (Cambridge, England), 48(71), 8889-8891 (2012-07-21)
Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to produce
Derek J Langeslay et al.
Analytical chemistry, 83(20), 8006-8010 (2011-09-15)
Sulfamate (NHSO(3)(-)) groups are critically important structural elements of the glycosaminoglycans heparin and heparan sulfate (HS). Experimental conditions are presented for detection of the sulfamate (1)H NMR resonances in aqueous solution. NMR spectra reported for N-sulfoglucosamine (GlcNS) and the synthetic
Hao Yu et al.
The Journal of organic chemistry, 78(17), 8427-8436 (2013-07-31)
Ph3P-catalyzed [3 + 2] cycloaddition reaction of sulfamate-derived cyclic imines with allenoate has been developed, affording sulfamate-fused dihydropyrroles under very mild conditions in high yields. Using amino acid-based bifunctional phosphine as chiral catalyst, its asymmetric variant provided the corresponding products
Jean-Yves Winum et al.
Bioorganic & medicinal chemistry letters, 22(14), 4681-4685 (2012-06-23)
A series of 50 sulfamates were obtained by reacting 4-aminophenol with isocyanates followed by sulfamoylation. Most of the new compounds were nanomolar inhibitors of the tumor-associated carbonic anhydrase (CA, EC 4.2.1.1) isoforms IX and XII, whereas they inhibited less cytosolic
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