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Merck

37442

Dihydroxyacetone phosphate lithium salt

≥95.0% (TLC)

Synonym(s):

1-Hydroxy-3-(phosphonooxy)-2-propanone lithium salt, DHAP, Glycerone phosphate lithium salt

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About This Item

Empirical Formula (Hill Notation):
C3H7O6P · xLi+
CAS Number:
Molecular Weight:
170.06 (free acid basis)
NACRES:
NA.32
PubChem Substance ID:
UNSPSC Code:
12352204
MDL number:

Product Name

Dihydroxyacetone phosphate lithium salt, ≥95.0% (TLC)

InChI

1S/C3H7O6P/c4-1-3(5)2-9-10(6,7)8/h4H,1-2H2,(H2,6,7,8)

SMILES string

OCC(COP(O)(O)=O)=O

InChI key

GNGACRATGGDKBX-UHFFFAOYSA-N

assay

≥95.0% (TLC)

form

powder

storage temp.

−20°C

Quality Level

Related Categories

Analysis Note

may contain up to 2-mol-equivalents water

Biochem/physiol Actions

Dihydroxyacetone phosphate (DHAP) is a metabolic intermediate involved in many pathways, including glycolysis, gluconeogenesis, glycerol metabolism, phosphatidic acid synthesis, fat metabolism, and the Calvin cycle.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Olga A Esakova et al.
Journal of the American Chemical Society, 141(36), 14142-14151 (2019-08-08)
Quinolinic acid is a common intermediate in the biosynthesis of nicotinamide adenine dinucleotide and its derivatives in all organisms that synthesize the molecule de novo. In most prokaryotes, it is formed from the condensation of dihydroxyacetone phosphate (DHAP) and iminoaspartate
Giovanni Covaleda-Cortés et al.
Marine drugs, 17(9) (2019-09-01)
A very powerful proteinaceous inhibitor of metallocarboxypeptidases has been isolated from the marine snail Nerita versicolor and characterized in depth. The most abundant of four, very similar isoforms, NvCla, was taken as reference and N-terminally sequenced to obtain a 372-nucleotide
John P Richard
Biochemistry, 51(13), 2652-2661 (2012-03-14)
Triosephosphate isomerase (TIM) catalyzes the stereospecific 1,2-proton shift at dihydroxyacetone phosphate (DHAP) to give (R)-glyceraldehyde 3-phosphate through a pair of isomeric enzyme-bound cis-enediolate phosphate intermediates. The chemical transformations that occur at the active site of TIM were well understood by
Christopher B Medina et al.
Nature, 580(7801), 130-135 (2020-04-03)
Caspase-dependent apoptosis accounts for approximately 90% of homeostatic cell turnover in the body1, and regulates inflammation, cell proliferation, and tissue regeneration2-4. How apoptotic cells mediate such diverse effects is not fully understood. Here we profiled the apoptotic metabolite secretome and
Glycerolipid biosynthesis in peroxisomes via the acyl dihydroxyacetone phosphate pathway.
A K Hajra et al.
Annals of the New York Academy of Sciences, 386, 170-182 (1982-01-01)

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