209058
Rhodium(II) acetate dimer
≥97%, powder
Synonym(s):
Rh2(OAc)4, Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
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About This Item
Linear Formula:
Rh2(OOCCH3)4
CAS Number:
Molecular Weight:
441.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
240-084-8
MDL number:
Quality Level
assay
≥97%
form
powder
reaction suitability
core: rhodium, reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
General description
Rhodium(II) acetate dimer is an effective catalyst for carbenoid reactions, hydrocarbon oxidation, hydroboration, and nitrene reactions.
Application
Effective catalyst for ylide formation.
Homogeneous catalyst.
Used in an efficient synthesis of β-hydroxy-α-arylacrylates involving the decomposition of diazoetster intermediates with concomitant 1,2-arylmigration.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Aldrichimica Acta, 15, 13-13 (1982)
Sugimura, T.; Mori, A.
Tetrahedron Asymmetry, 14, 881-881 (2003)
Dirhodium(II) Tetraacetate
Michael P, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)