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Merck

548014

Diphenyliodonium hexafluorophosphate

≥98%

Synonym(s):

DPIHFP

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About This Item

Linear Formula:
(C6H5)2I(PF6)
CAS Number:
58109-40-3
Molecular Weight:
426.08
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
24879004
EC Number:
261-134-5
Beilstein/REAXYS Number:
4343861
MDL number:
MFCD00061398

Key Documents

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Product Name

Diphenyliodonium hexafluorophosphate, ≥98%

InChI key

DSSRLRJACJENEU-UHFFFAOYSA-N

InChI

1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1

SMILES string

F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2

assay

≥98%

mp

140-144 °C (lit.)

Quality Level

200

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Related Categories

Application

Cationic photoinitiator. Photoacid generator.

Packaging

Packaged in amber poly bottles

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0268
BCCM8630
BCCL6521
BCCK4517
BCCJ2292

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C M F Hardy et al.
Dental materials : official publication of the Academy of Dental Materials, 34(9), 1278-1288 (2018-06-03)
To determine the limitations of using light-curable resin-based luting composites (RBLCs) to bond indirect ceramic/resin-composite restorations by measuring light transmittance through indirect restorative materials and the resulting degree of conversion (DC) of the luting-composites placed underneath. Various thicknesses (0-4mm) and
Alinne Segatto Pires Altmann et al.
The Angle orthodontist, 87(5), 759-765 (2017-07-08)
The aim of this study was to develop an experimental orthodontic adhesive and evaluate how adding phosphate invert glass containing niobium pentoxide (PIG-Nb) affected the adhesive's properties. PIG-Nb was added at 1, 2.5, and 5 wt% to experimental adhesive (75
Rizacan Sarikaya et al.
Polymers, 12(9) (2020-09-17)
The inherent degradation property of most dental resins in the mouth leads to the long-term release of degradation by-products at the adhesive/tooth interface. The by-products increase the virulence of cariogenic bacteria, provoking a degradative positive-feedback loop that leads to physicochemical
Monika Topa et al.
Sensors (Basel, Switzerland), 20(11) (2020-05-31)
Novel fluorescent sensors with electron-donating or electron-withdrawing substituents incorporated into a chromophore group based on 2,6-diphenylpyridine were designed and synthesised. The spectroscopic properties of these compounds were studied. Moreover, the positive solvatochromism of 2,6-bis-(4-methylsulphanylphenyl)pyridine (PT-SCH3) in selected solvents was studied
Aurélien Bigot et al.
Journal of the American Chemical Society, 133(35), 13778-13781 (2011-08-19)
A new strategy for the catalytic enantioselective α-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied
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