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Merck

248401

Magnesium methyl carbonate solution

2.0 M in DMF

Synonym(s):

MMC, Methoxymagnesium methyl carbonate, Methyl methoxymagnesium carbonate, Stile’s reagent

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About This Item

Linear Formula:
CH3OMgOCO2CH3
CAS Number:
Molecular Weight:
130.38
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4342967
Form:
liquid
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form

liquid

Quality Level

concentration

2.0 M in DMF

density

1.103 g/mL at 25 °C

SMILES string

CO[Mg]OC(=O)OC

InChI

1S/C2H4O3.CH3O.Mg/c1-5-2(3)4;1-2;/h1H3,(H,3,4);1H3;/q;-1;+2/p-1

InChI key

PNVKCUSCADAAMP-UHFFFAOYSA-M

General description

Magnesium methyl carbonate is also known as Stile′s reagent. It is used as a carboxylating agent for the α-carboxylation of nitroalkanes, ketones, lactones, hydantoins, and phenols.

signalword

Danger-Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

136.4 °F - closed cup

flash_point_c

58 °C - closed cup


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Chen Ling et al.
Cell discovery, 2, 16047-16047 (2017-01-07)
The recruitment of FANCM, a conserved DNA translocase and key component of several DNA repair protein complexes, to replication forks stalled by DNA interstrand crosslinks (ICLs) is a step upstream of the Fanconi anemia (FA) repair and replication traverse pathways
Mara Colombo et al.
Human mutation, 39(5), 729-741 (2018-02-21)
Although the spliceogenic nature of the BRCA2 c.68-7T > A variant has been demonstrated, its association with cancer risk remains controversial. In this study, we accurately quantified by real-time PCR and digital PCR (dPCR), the BRCA2 isoforms retaining or missing exon 3.
Sebastiano Di Bucchianico et al.
Particle and fibre toxicology, 15(1), 32-32 (2018-07-19)
Genotoxicity is an important toxicological endpoint due to the link to diseases such as cancer. Therefore, an increased understanding regarding genotoxicity and underlying mechanisms is needed for assessing the risk with exposure to nanoparticles (NPs). The aim of this study
Tao Chen et al.
IEEE transactions on pattern analysis and machine intelligence, 40(10), 2522-2528 (2017-09-30)
The marriage between the deep convolutional neural network (CNN) and region proposals has made breakthroughs for object detection in recent years. While the discriminative object features are learned via a deep CNN for classification, the large intra-class variation and deformation
Masanori Toyofuku et al.
Nature communications, 8(1), 481-481 (2017-09-09)
Bacteria release membrane vesicles (MVs) that play important roles in various biological processes. However, the mechanisms of MV formation in Gram-positive bacteria are unclear, as these cells possess a single cytoplasmic membrane that is surrounded by a thick cell wall.

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