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579726

Grubbs Catalyst® M102

97%, Umicore

Synonym(s):

Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II), Grubbs Catalyst® 1st Generation, Grubbs Catalyst® M1a (C823)

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About This Item

Empirical Formula (Hill Notation):
C43H72Cl2P2Ru
CAS Number:
172222-30-9
Molecular Weight:
822.96
MDL number:
MFCD01074452
UNSPSC Code:
12161600
PubChem Substance ID:
24881009
NACRES:
NA.22
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Product Name

Grubbs Catalyst® M102, Umicore, 97%

Quality Level

100

product line

Grubbs Catalyst® M100 Series

assay

97%

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Ring-Opening Polymerization

manufacturer/tradename

Umicore Grubbs Catalyst® M100 Series

mp

153 °C (dec.)

storage temp.

2-8°C

SMILES string

C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

Application

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.

Learn more about our metathesis catalysts

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Legal Information

Product of Umicore

Additional information available at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB5423
MKCZ9619
MKCZ3539
MKCX9401
MKCX5593

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Related Content

Olefin Metathesis Application Guide

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

Brummer, O.; Ruckert, a.; Blechert, S.
Chemistry (Weinheim An Der Bergstrasse, Germany), 3, 441-441 (1997)
Charvet, R.: Novak, B. M.
Macromolecules, 34, 7680-7680 (2001)
Michaut, M.; Parrain, J.-L.; Santelli, M.
Chemical Communications (Cambridge, England), 2567-2567 (1998)
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