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537713

4-Methyl-2-pentanone

≥99%

Synonym(s):

Isobutyl methyl ketone, Isopropylacetone, MIBK, Methyl isobutyl ketone

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About This Item

Linear Formula:
(CH3)2CHCH2COCH3
CAS Number:
108-10-1
Molecular Weight:
100.16
UNSPSC Code:
12352115
NACRES:
NA.21
PubChem Substance ID:
329757992
EC Number:
203-550-1
Beilstein/REAXYS Number:
605399
MDL number:
MFCD00008938
Assay:
≥99%
Bp:
117-118 °C
Vapor pressure:
15.7 mmHg
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vapor density

3.5 (vs air)

Quality Segment

100

vapor pressure

15.7 mmHg

assay

≥99%

autoignition temp.

840 °F

expl. lim.

1.2-8 %, 93 °F

impurities

≤0.1000% (water)

refractive index

n20/D 1.395 (lit.)

bp

117-118 °C

mp

−80 °C (lit.)

solubility

water: soluble 20 g/L

density

0.801 g/mL at 25 °C (lit.)

SMILES string

CC(C)CC(C)=O

InChI

1S/C6H12O/c1-5(2)4-6(3)7/h5H,4H2,1-3H3

InChI key

NTIZESTWPVYFNL-UHFFFAOYSA-N

General description

4-Methyl-2-pentanone (Methyl isobutyl ketone, MIBK), an aliphatic ketone, is commonly used as an organic solvent. It is generally used as an extractant in atomic absorption spectrometry. Preparation of MIBK using 2-propanol as the precursor has been reported with yield as high as 25%. The rate constant for the reaction between OH radical and MIBK was found to be 1.40 ± 0.07×1011cm3molecule-1s-1. The kinetics and mechanism of photochemical reaction of MIBK in n-hexane solution has been studied. The microwave spectrum of MIBK has been recorded to obtain its rotational constants and centrifugal distortion constants.

Application

4-Methyl-2-pentanone may be used to prepare (R)-(-)-4-methyl-2-pentanol via asymmetric hydrogenation in the presence of silica-supported starch-polysulfosiloxane-platinum complex (SiO2-ST-Si-S-Pt).

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Carc. 2 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH066

Storage Class

3 - Flammable liquids

flash_point_f

57.2 °F - closed cup

flash_point_c

14 °C - closed cup

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