213462
Borohydrure de sodium
ReagentPlus®, 99%
Synonyme(s) :
Tétrahydruroborate de sodium
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A propos de cet article
Formule linéaire :
NaBH4
Numéro CAS:
Poids moléculaire :
37.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
241-004-4
MDL number:
Assay:
99%
Form:
powder
Service technique
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Laissez-nous vous aiderQuality Level
product line
ReagentPlus®
assay
99%
form
powder
reaction suitability
reagent type: reductant
mp
>300 °C (dec.) (lit.)
SMILES string
[BH4-].[Na+]
InChI
1S/BH4.Na/h1H4;/q-1;+1
InChI key
YOQDYZUWIQVZSF-UHFFFAOYSA-N
General description
Sodium borohydride, also known as sodium tetrahydridoborate, is a highly basic boron hydride that is commonly used as a reducing agent. It reacts very slowly with water and acts as a catalyst and stabilizer.
Application
Sodium borohydride can be used as a reducing agent for the:
- Synthesis of cobalt (II, III) oxide (Co3O4) from cobalt chloride (CoCl2) via a co-reduction process.
- Solvent-free reduction of aldehydes and ketones to alcohols in the presence of solid acid as an activator.
- Reductive amination of carbonyl compounds to secondary amines in the presence of silica-gel-supported sulfuric acid as a catalyst.
- Raney nickel-catalyzed reduction of aromatic nitro compounds to aromatic amines.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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Danger
hcodes
supp_hazards
Classe de stockage
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1
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Sodium borohydride versus ammonia borane, in hydrogen storage and direct fuel cell applications
Umit DB,et al.
Energy & Environmental Science, 2, 627-637 (2009)
Magnetic Co 3 O 4/reduced graphene oxide nanocomposite as a superior heterogeneous catalyst for one-pot oxidative esterification of aldehydes to methyl esters
Vineeta P,et al.
Royal Society of Chemistry Advances, 5, 88567-88573 (2015)
Kinetics of Ru-catalyzed sodium borohydride hydrolysis
JS Z,et al.
Journal of Power Sources, 164, 772-781 (2007)