163015
Thallium(III) nitrate trihydrate
Synonym(s):
TTN, Thallium trinitrate
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About This Item
Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
Molecular Weight:
444.44
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-325-4
MDL number:
Quality Level
reaction suitability
core: thallium, reagent type: catalyst
mp
102-105 °C (lit.)
SMILES string
O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
InChI key
ZCPIKMRXMBJLCP-UHFFFAOYSA-N
Application
Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
Storage Class
5.1B - Oxidizing hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
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Enrico Bugiardini et al.
Frontiers in neurology, 9, 456-456 (2018-07-13)
Objective: Distal myopathies are a diagnostically challenging group of diseases. We wanted to understand the value of MRI in the current clinical setting and explore the potential for optimizing its clinical application. Methods: We retrospectively audited the diagnostic workup in
Synthetic Communications, 9, 301-301 (1979)
Kevin Yauy et al.
The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations