705551
Hydrogen chloride solution
3 M in cyclopentyl methyl ether (CPME)
Synonym(s):
Hydrochloric acid in CPME
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About This Item
Empirical Formula (Hill Notation):
HCl
CAS Number:
Molecular Weight:
36.46
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Concentration:
2.85-3.30 M (silver nitrate titration), 3 M in cyclopentyl methyl ether (CPME)
Form:
liquid
form
liquid
Quality Level
concentration
2.85-3.30 M (silver nitrate titration), 3 M in cyclopentyl methyl ether (CPME)
bp
106 °C
density
0.895 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Cl
InChI
1S/ClH/h1H
InChI key
VEXZGXHMUGYJMC-UHFFFAOYSA-N
Application
Hydrogen chloride solution can be used in the Pinner synthesis of imidate hydrochlorides, which involves acid-catalyzed condensation of a nitrile and an alcohol under anhydrous conditions.
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
flash_point_f
50.0 °F
flash_point_c
10 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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The Chemistry of Imidates.
Roger R and Neilson D G
Chemical Reviews, 61(2), 179-211 (1961)
Douglas M McMillan et al.
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Davide R Ceratti et al.
Advanced materials (Deerfield Beach, Fla.), 27(34), 4958-4962 (2015-07-23)
A new, simple bi-phasic dip-coating method is developed. This method is considered as a great improvement of the technique for research, development and production, since expensive, rare, harmful, or time-evolving solutions can now be easily deposited on large surfaces and