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Merck

07-4260

N,N-Dimethylaniline

SAJ first grade, ≥99.0%

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About This Item

Linear Formula:
C6H5N(CH3)2
CAS Number:
121-69-7
Molecular Weight:
121.18
PubChem Substance ID:
329748438
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
507140
MDL number:
MFCD00008304

Key Documents

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Product Name

N,N-Dimethylaniline, SAJ first grade, ≥99.0%

SMILES string

CN(C)c1ccccc1

InChI

1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

JLTDJTHDQAWBAV-UHFFFAOYSA-N

grade

SAJ first grade

assay

≥99.0%

form

liquid

availability

available only in Japan

refractive index

n20/D 1.557 (lit.)

pH

7.4 (20 °C, 1.2 g/L)

bp

193-194 °C (lit.)

mp

1.5-2.5 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

143.6 °F

flash_point_c

62 °C

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Certificates of Analysis (COA)

Lot/Batch Number
A3022
A3736
A1443
A1190
A9143

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Marius Koch et al.
Journal of the American Chemical Society, 134(8), 3729-3736 (2012-01-31)
The fluorescence quenching of 3-cyanoperylene upon electron transfer from N,N-dimethylaniline in three room-temperature ionic liquids (RTILs) and in binary solvent mixtures of identical viscosity has been investigated using steady-state and time-resolved fluorescence spectroscopy. This study was stimulated by previous reports
Yong Wang et al.
The journal of physical chemistry. B, 114(8), 2964-2970 (2010-02-12)
This paper addresses the experimentally observed mechanistic differences between the cytochrome P450-catalyzed N-demethylation of substituted N,N-dimethylanilines (DMA) and of N,N-dimethylbenzamides (DMBA). The two reactions of these substrates are initiated by C-H activation of the methyl groups on the nitrogen. Thus
Kefeng Liu et al.
Dalton transactions (Cambridge, England : 2003), 41(12), 3461-3467 (2012-02-04)
A number of new half-sandwich zirconium(IV) complexes bearing N,N-dimethylaniline-amido ligands with the general formula Cp*ZrCl(2)[ortho-(RNCH(2))(Me(2)N)C(6)H(4)] [R = 2,6-Me(2)C(6)H(3) (1), 2,6-(i)Pr(2)C(6)H(3) (2), (i)Pr (3), (t)Bu (4)] were synthesized by the reaction of Cp*ZrCl(3) with the corresponding ortho-(Me(2)N)C(6)H(4)CH(2)NRLi. All new zirconium complexes
Cai-Rong Zhang et al.
Journal of molecular graphics & modelling, 38, 419-429 (2012-11-03)
The photon to current conversion efficiency of dye-sensitized solar cells (DSCs) can be significantly affected by dye sensitizers. The design of novel dye sensitizers with good performance in DSCs depend on the dye's information about electronic structures and optical properties.
Haijun Li et al.
Organic letters, 11(18), 4176-4179 (2009-08-18)
Methylene-bridged bis-1,3-dicarbonyl derivatives were synthesized efficiently by iron-catalyzed oxidative reactions of 1,3-dicarbonyl compounds and N,N-dimethylaniline. Bipyrazoles and substituted 1,4-dihydropyridine were obtained by the reactions of bis-1,3-dicarbonyl compounds with hydrazines and ammonium acetate, respectively.
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