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Merck

13-1520

Hydrazine monohydrate

SAJ first grade, ≥98.0%

Synonym(s):

Hydrazinium hydroxide

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About This Item

Linear Formula:
NH2NH2 · H2O
CAS Number:
7803-57-8
Molecular Weight:
50.06
PubChem Substance ID:
329750028
UNSPSC Code:
12352300
Beilstein/REAXYS Number:
878137
MDL number:
MFCD00149931

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Product Name

Hydrazine monohydrate, SAJ first grade, ≥98.0%

SMILES string

O.NN

InChI

1S/H4N2.H2O/c1-2;/h1-2H2;1H2

InChI key

IKDUDTNKRLTJSI-UHFFFAOYSA-N

grade

SAJ first grade

vapor density

>1 (vs air)

vapor pressure

5 mmHg ( 25 °C)

assay

≥98.0%

form

liquid

expl. lim.

99.99 %

availability

available only in Japan

refractive index

n20/D 1.428 (lit.)

pH

10.6-10.7 (10 g/L)

bp

120.1 °C (lit.)

mp

−51.7 °C (lit.)

density

1.032 g/mL at 25 °C (lit.)

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
A5535
A4445
A3432
A1445
A0352

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Weidong Qu et al.
Biosensors & bioelectronics, 42, 430-433 (2012-12-19)
Graphene-nickel nanoparticle hybrid was prepared by the one-step far infrared-assisted reduction of graphene oxide and nickel (II) ions using hydrazine. It was loaded on the surface of a magnetic electrode for electrochemical sensing. The feasibility and performance of the novel
Timothy M Alligrant et al.
Lab on a chip, 13(3), 349-354 (2012-12-06)
We report on real-time electrochemical detection of individual DNA hybridization events at an electrode surface. The experiment is carried out in a microelectrochemical device configured with a working electrode modified with single-stranded DNA probe molecules. When a complementary DNA strand
Erika Lattová et al.
Mass spectrometry reviews, 32(5), 366-385 (2013-01-25)
Over the last years, extensive studies have evaluated glycans from different biological samples and validated the importance of glycosylation as one of the most important post-translational modifications of proteins. Although a number of new methods for carbohydrate analysis have been
Mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow: application to the synthesis of functionalized heterocycles.
Andrew DeAngelis et al.
Angewandte Chemie (International ed. in English), 52(12), 3434-3437 (2013-02-14)
Leslie D Field et al.
Inorganic chemistry, 52(3), 1570-1583 (2013-01-24)
Treatment of [RuCl(PP(3)(iPr))](+)Cl(-) (PP(3)(iPr) = P(CH(2)CH(2)P(i)Pr(2))(3)) with hydrazine, phenylhydrazine, and methylhydrazine afforded side-on bound hydrazine complexes [RuCl(η(2)-H(2)N-NH(2))(η(3)-PP(3)(iPr))](+), [RuCl(η(2)-H(2)N-NHPh)(η(3)-PP(3)(iPr))](+), and [RuCl(η(2)-H(2)N-NHMe)(η(3)-PP(3)(iPr))](+). The analogous reactions of [RuCl(2)(PP(3)(Ph))] (PP(3)(Ph) = P(CH(2)CH(2)PPh(2))(3)) with hydrazine, phenylhydrazine, and methylhydrazine afforded end-on bound hydrazine complexes [RuCl(η(1)-H(2)N-NH(2))(PP(3)(Ph))](+), [RuCl(η(1)-H(2)N-NHPh)(PP(3)(Ph))](+)
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