G6875
α-D-Glucose 1-phosphate dipotassium salt hydrate
≥97% (HPLC)
Synonym(s):
α-D-Glucopyranose 1-phosphate, Cori ester
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About This Item
Empirical Formula (Hill Notation):
C6H11K2O9P · xH2O
CAS Number:
Molecular Weight:
336.32 (anhydrous basis)
MDL number:
UNSPSC Code:
12352201
NACRES:
NA.25
biological source
synthetic
Quality Level
assay
≥97% (HPLC)
form
powder
impurities
glucose, essentially free
color
white
solubility
water: slightly soluble 50 g/L
storage temp.
−20°C
SMILES string
[K+].[K+].[H]O[H].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@@H]1O
InChI
1S/C6H13O9P.2K.H2O/c7-1-2-3(8)4(9)5(10)6(14-2)15-16(11,12)13;;;/h2-10H,1H2,(H2,11,12,13);;;1H2/q;2*+1;/p-2/t2-,3-,4+,5-,6-;;;/m1.../s1
InChI key
VOQGDSVKCMGEFO-FBNUBEQJSA-L
General description
α-D-Glucose 1-phosphate is the α-anomeric form of glucose which contains a phosphate group on the primary carbon. It can be converted into the deoxysugar CDP-glucose by the enzyme α-D-Glucose-1-phosphate cytidylyltransferase.
Preparation Note
Prepared by a modification of the procedure of McCready, R.M., et al., J. Am. Chem. Soc., 66, 560 (1944).
Other Notes
Formerly listed as Grade I.
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Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Jef Van der Borght et al.
Biotechnology journal, 5(9), 986-993 (2010-08-28)
β-D-Glucose-1-phosphate (βGlc1P) is an efficient glucosyl donor for both enzymatic and chemical glycosylation reactions but is currently very costly and not available in large amounts. This article provides an efficient production method of βGlc1P from trehalose and phosphate using the
Stanley A Blumenthal
Perspectives in biology and medicine, 55(2), 236-249 (2012-05-31)
In 1945, Earl Sutherland (1915-1974) [corrected] and associates began studies of the mechanism of hormone-induced glycogen breakdown in the liver. In 1956, their efforts culminated in the identification of cyclic AMP, an ancient molecule generated in many cell types in
Bijay Singh et al.
Protein engineering, design & selection : PEDS, 25(4), 179-187 (2012-02-16)
Two similar genes, dnmL and rmbA in Streptomyces peucetius, which encode for glucose-1-phosphate (G-1-P) thymidylyltransferases were expressed in Escherichia coli under similar conditions. While RmbA was expressed in soluble form, DnmL was found as insoluble aggregates in inclusion bodies. The