537365
Methyl acetoacetate
ReagentPlus®, ≥98.5% (GC)
Sinónimos:
MAA, 3-Oxobutanoic acid methyl ester, Acetoacetic acid methyl ester
Iniciar sesión para ver los precios por organización y contrato.
Seleccione un Tamaño
Cambiar Vistas
Acerca de este artículo
Fórmula lineal:
CH3COCH2COOCH3
Número CAS:
Peso molecular:
116.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-299-8
Beilstein/REAXYS Number:
506727
MDL number:
Assay:
≥98.5% (GC)
Servicio técnico
¿Necesita ayuda? Nuestro equipo de científicos experimentados está aquí para ayudarle.
Permítanos ayudarleQuality Level
product line
ReagentPlus®
assay
≥98.5% (GC)
autoignition temp.
536 °F
manufacturer/tradename
Sigma-Aldrich
refractive index
n20/D 1.419 (lit.)
bp
169-170 °C/70 mmHg (lit.)
mp
−80 °C (lit.)
density
1.076 g/mL at 25 °C (lit.)
functional group
ester, ketone
SMILES string
COC(=O)CC(C)=O
InChI
1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3
InChI key
WRQNANDWMGAFTP-UHFFFAOYSA-N
Application
Methyl acetoacetate (MAA) can be used as a reactant for:
- Transesterification with alcohols by using various catalysts.
- The synthesis of 4-methylcoumarins with phenol in presence of zinc and I2 as catalysts.
- Asymmetric heterogeneous hydrogenation reactions by transition metal catalysts.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Still not finding the right product?
Explore all of our products under Methyl acetoacetate
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1
Clase de almacenamiento
10 - Combustible liquids
wgk
WGK 1
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Elija entre una de las versiones más recientes:
¿Ya tiene este producto?
Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Enantioselective hydrogenation of methyl acetoacetate catalyzed by nickel supported on activated carbon or graphite.
Wolfson A, et al.
Applied Catalysis A: General, 208(1-2), 91-98 (2001)
Synergism between microwave and enzyme catalysis in intensification of reactions and selectivities: transesterification of methyl acetoacetate with alcohols.
Yadav GD and Lathi PS
J. Mol. Catal. A: Chem., 223(1-2), 51-56 (2004)
Zinc mediated transesterification of ?-ketoesters and coumarin synthesis.
Chavan SP, et al.
Tetrahedron Letters, 43(47), 8583-8586 (2002)