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563110

Diethyl azodicarboxylate solution

40 wt. % in toluene

Sinónimos:

1,2-Ethoxycarbonyl diazene solution, DEAD, Diethoxycarbonyldiazene solution, Diethyl azodiformate solution, NSC 3474, NSC 679015, Unifoam AZ-AE 200

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Fórmula lineal:
C2H5OCON=NCOOC2H5
Número CAS:
1972-28-7
Peso molecular:
174.15
PubChem Substance ID:
24880080
UNSPSC Code:
12352108
Beilstein/REAXYS Number:
908662
MDL number:
MFCD00009103
Servicio técnico
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concentration

40 wt. % in toluene

refractive index

n20/D 1.4690

bp

116-117 °C

density

0.956 g/mL at 25 °C

functional group

azo

storage temp.

2-8°C

SMILES string

CCOC(=O)\N=N/C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

General description

DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.

Application

A commonly used activating reagent in Mitsunobo reactions.
Reactant for preparation of:
  • Immunostimulants α-Galactosylceramides
  • Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases
  • Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase
  • Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities
  • Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes

Reagent for:
  • Annulation of N-protected imines
  • α-thiocyanation of enolizable ketones with ammonium thiocyanate
  • Diels-Alder reactions

Packaging

100g unit contains ca. 40g DEAD solute
25g unit contains ca. 10g DEAD solute

Disclaimer

Toxic, Irritant, Flammable

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signalword

Danger

target_organs

Central nervous system, Respiratory system

Clase de almacenamiento

5.2 - Organic peroxides and self-reacting hazardous materials

flash_point_f

105.8 °F - closed cup

flash_point_c

41 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Self-react. C - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

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Certificados de análisis (COA)

Lot/Batch Number
MKCM8638
MKCL0488
MKCJ1314
MKCF3967
MKCC6724

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