A10701
Acetofenona
99%, liquid, ReagentPlus®
Sinónimos:
Metilfenilcetona
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Acerca de este artículo
Fórmula lineal:
CH3COC6H5
Número CAS:
Peso molecular:
120.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-708-7
MDL number:
Beilstein/REAXYS Number:
605842
Assay:
99%
Form:
liquid
Servicio técnico
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Permítanos ayudarleNombre del producto
Acetofenona, ReagentPlus®, 99%
vapor density
4.1 (vs air)
Quality Level
vapor pressure
0.45 mmHg ( 25 °C), 1 mmHg ( 15 °C)
product line
ReagentPlus®
assay
99%
form
liquid
autoignition temp.
1058 °F
refractive index
n20/D 1.534 (lit.)
bp
202 °C (lit.)
mp
19-20 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
SMILES string
CC(=O)c1ccccc1
InChI
1S/C8H8O/c1-7(9)8-5-3-2-4-6-8/h2-6H,1H3
InChI key
KWOLFJPFCHCOCG-UHFFFAOYSA-N
General description
Acetophenone is an aromatic ketone used in the synthesis of alcohol by catalytic hydrogenation, and also in perfumery.
Acetophenone (AP, methyl phenyl ketone) is a common industrial solvent. It can be synthesized from 1-phenylethanol in the presence of PdAu-NPs-TiO2 (titanium dioxide-supported palladium gold bimetallic nanoparticles) hybrid. Its vacuum ultraviolet absorption spectrum shows absorption bands at 196, 191, 179 and 167mμ. AP reacts with α-naphtylphenylsilane in the presence of N-chelate ligands based on chiral oxazolines to undergo hydrosilylation with high enantioselectivity. It can also undergo hydrogenation reaction in the presence of different transition metal catalysts under different conditions.
Acetophenone (AP, methyl phenyl ketone) is a common industrial solvent. It can be synthesized from 1-phenylethanol in the presence of PdAu-NPs-TiO2 (titanium dioxide-supported palladium gold bimetallic nanoparticles) hybrid. Its vacuum ultraviolet absorption spectrum shows absorption bands at 196, 191, 179 and 167mμ. AP reacts with α-naphtylphenylsilane in the presence of N-chelate ligands based on chiral oxazolines to undergo hydrosilylation with high enantioselectivity. It can also undergo hydrogenation reaction in the presence of different transition metal catalysts under different conditions.
Application
Acetophenone was used to induce peak currents in M71 neurons using voltage clamp. It may be used in the synthesis of N-(1-phenylethyl)formamide, via Leuckart reaction.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
Clase de almacenamiento
10 - Combustible liquids
wgk
WGK 1
flash_point_f
179.6 °F - closed cup
flash_point_c
82 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Jiwei He et al.
The European journal of neuroscience, 36(4), 2452-2460 (2012-06-19)
Early experience considerably modulates the organization and function of all sensory systems. In the mammalian olfactory system, deprivation of the sensory inputs via neonatal, unilateral naris closure has been shown to induce structural, molecular and functional changes from the olfactory
Green-chemistry Compatible Approach to TiO2-supported PdAu Bimetallic Nanoparticles for Solvent-free 1-Phenylethanol Oxidation under Mild Conditions.
Chang JB, et al.
Nano-Micro Letters, 7(3), 307-315 (2015)
Photocatalytic reduction of acetophenone in membrane reactors under UV and visible light using TiO2 and Pd/TiO2 catalysts.
Molinari R, et al.
Chemical Engineering Journal, 274, 307-316 (2015)