12322
Iron(III) chloride solution
purum, 45% FeCl3 basis
Sinónimos:
Ferric chloride solution
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Fórmula lineal:
FeCl3
Número CAS:
Peso molecular:
162.20
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
liquid
Servicio técnico
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Permítanos ayudarleQuality Level
grade
purum
form
liquid
reaction suitability
reagent type: catalyst
core: iron
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
concentration
45% (FeCl3)
greener alternative category
, Aligned
SMILES string
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI key
RBTARNINKXHZNM-UHFFFAOYSA-K
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. The iron catalysts are known to be inexpensive and environmentally benign. Click here for more information.
Iron(III) chloride is a mild oxidizing agent. It is widely employed as a Lewis acid in organic synthesis. On crystallization with water, it forms hydrates. It can be prepared by passing chlorine over scrap iron at approximately 650°C.
Application
Iron(III) chloride may be used for the polymerization of pyrrole and for the preparation of the phenanthrene ring. It is widely employed for the following reactions:
- polymerizations
- oxidations
- oxidative couplings
- reductions
- C−C bond formation
- Ferrier rearrangement
- one-pot multicomponent condensations
- Friedel-Crafts reactions
- cyclization′s
- glycosidation
- Prins-type cyclisation
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1
Clase de almacenamiento
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Recent uses of iron (III) chloride in organic synthesis.
Diaz DD, et al.
Current Organic Chemistry, 10(4), 457-476 (2006)
Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Armes SP.
Synthetic Metals, 20(3), 365-371 (1987)
Kailiang Wang et al.
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic