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Merck

239321

Sulfito de sodio

ACS reagent, ≥98.0%

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Fórmula lineal:
Na2SO3
Número CAS:
Peso molecular:
126.04
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-821-4
MDL number:
Assay:
≥98.0%
Grade:
ACS reagent
Form:
powder or crystals
Solubility:
water: soluble 126 g/L at 20 °C
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grade

ACS reagent

Quality Level

agency

suitable for SM 5210

assay

≥98.0%

form

powder or crystals

impurities

Free acid, passes test, ≤0.005% insolubles, ≤0.03 meq/g Titr. free base

pH

9.0-10.5 (25 °C, 126 g/L)

solubility

water: soluble 126 g/L at 20 °C

anion traces

chloride (Cl-): ≤0.02%

cation traces

Fe: ≤0.001%, heavy metals (as Pb): ≤0.001%

SMILES string

[Na+].[Na+].[O-]S([O-])=O

InChI

1S/2Na.H2O3S/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2

InChI key

GEHJYWRUCIMESM-UHFFFAOYSA-L

General description

Sodium sulfite is a water-soluble inorganic salt that is commonly used as a reducing agent. It is also used for sulfonation and sulfomethylation reactions. Additionally, it is used in the textile industry as a bleaching, de-sulfurizing, and dechlorinating agent. As an oxygen and free chlorine scavenger, Na2SO3 is employed in the water treatment process. Sodium sulfite participates in the purification and isolation of aldehydes and ketones by forming adducts with them. Other uses include the production of sodium thiosulfate, detergents, and dyes.

Application

Sodium sulfite can be used:
  • As a reducing agent in the hydroxylation of arylboronic acids and arylboronic esters into corresponding phenols.
  • In the transformation of α-amino alcohol methanesulfonate hydrochlorides to sodium α-amino alkanesulfonates.
  • As a SO2 precursor in the multigram synthesis of DABCO·(SO2)2 abbreviated as DABSO.



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Clase de almacenamiento

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Reaction kinetics of sodium sulfite oxidation by the rapid-mixing method.
Barron CH and O'Hern HA.
Chemical Engineering Science, 21(5), 397-404 (1966)
New plasticizers for wheat gluten films.
Irissin-Mangata J, et al.
European Polymer Journal, 37(8), 1533-1541 (2001)
Amber R Boles et al.
Biotechnology and bioengineering, 109(3), 637-646 (2011-10-22)
A novel sulfur-utilizing perchlorate reducing bacterial consortium successfully treated perchlorate (ClO₄⁻) in prior batch and bench-scale packed bed reactor (PBR) studies. This study examined the scale up of this process for treatment of water from a ClO ₄⁻ and RDX contaminated