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Merck

31293

Copper(II) sulfate pentahydrate

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99-102%

Sinónimos:

Cupric sulfate pentahydrate, Sulfuric acid, copper(II) salt (1:1) pentahydrate

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Fórmula lineal:
CuSO4 · 5H2O
Número CAS:
Peso molecular:
249.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
99-102%
Form:
solid
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Quality Level

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor pressure

7.3 mmHg ( 25 °C)

grade

ACS reagent, puriss. p.a.

assay

99-102%

form

solid

impurities

≤0.001% total nitrogen (N), ≤0.005% in water insoluble matters

pH

3.7-4.5 (20 °C, 5%)

mp

110 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg

cation traces

As: ≤0.5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤10 mg/kg, Fe: ≤20 mg/kg, K: ≤10 mg/kg, Mg: ≤5 mg/kg, Na: ≤20 mg/kg, Ni: ≤20 mg/kg, Pb: ≤20 mg/kg, Zn: ≤300 mg/kg

SMILES string

O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O

InChI

1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

InChI key

JZCCFEFSEZPSOG-UHFFFAOYSA-L

General description

Copper(II) sulfate pentahydrate (CuSO4·5H2O, Blue vitriol) is a hydrated copper(II) salt. It undergoes hydrothermal reactions with the tripodal ligands to afford metal-organic frameworks (MOFs). CuSO4·5H2O along with metallic copper was employed as a catalyst for the synthesis of different ligand-arm functionalized azoamides. On heating above 560°C, it decomposes to CuO.

Application

Copper(II) sulfate pentahydrate may be employed in the following studies:
  • As a catalyst for the acetylation of alcohols and phenols under solvent-free conditions.
  • To compose the electrolyte for the electrodeposition of Cu-Zn-Sn precursors, required for the preparation of Cu2ZnSnS4 (CZTS) thin films.
  • As catalyst for the dehydration of alcohols.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Clase de almacenamiento

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Hangil Moon et al.
Materials (Basel, Switzerland), 13(5) (2020-03-11)
Despite the widespread application of activated carbon fiber (ACF) filters in air cleaning owing to their high surface area and low price, they have certain limitations in that they facilitate bacterial growth upon prolonged use as ACF filters can provide
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)