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Merck

252387

Pentafluoropropionic anhydride

99%

Synonym(s):

PFPA, Perfluoropropionic anhydride

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About This Item

Linear Formula:
(CF3CF2CO)2O
CAS Number:
356-42-3
Molecular Weight:
310.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24855205
EC Number:
206-604-2
Beilstein/REAXYS Number:
1806446
MDL number:
MFCD00000429

Key Documents

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Product Name

Pentafluoropropionic anhydride, 99%

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

SMILES string

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

assay

99%

form

liquid

bp

69-70 °C/735 mmHg (lit.)

density

1.571 g/mL at 25 °C (lit.)

functional group

anhydride
ester
fluoro

Quality Level

100

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Application

Pentafluoropropionic anhydride was used:
  • in preparation of halogenated derivatives of phenolic acids, required for determination of some biologically important acids in cerebrospinal fluid
  • as derivatization reagent in detection of 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain by GC-multiple ion detection
  • in simultaneous determination of the major metabolites of dopamine in rat striatum by gas-liquid chromatography

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB1232
SDBB1471
STBK5958
STBK3993
STBK3532

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M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
G F Grinstead
Journal of analytical toxicology, 15(6), 293-298 (1991-11-01)
PFPA and acetic anhydride derivatives of morphine and codeine were evaluated with respect to stability, chromatography, potential for analytical interferences by other opiates, and suitability of major fragment ions for analysis by GC/MS with deuterated internal standards and selected ion
E Ballesteros et al.
Analytical chemistry, 65(13), 1773-1778 (1993-07-01)
A new analytical method that combines on-line derivatization-extraction and gas-liquid chromatography for the determination of N-methylcarbamates is reported. The hydrolysis products of N-methylcarbamates (phenols) are derivatized and extracted in a continuous fashion using pentafluoropropionic anhydride (derivatizing reagent) in n-hexane as
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