Skip to Content
Merck

346276

Tetrakis(acetonitrile)copper(I) hexafluorophosphate

97%, solid

Synonym(s):

Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
[(CH3CN)4Cu]PF6
CAS Number:
64443-05-6
Molecular Weight:
372.72
UNSPSC Code:
12161600
PubChem Substance ID:
24861387
NACRES:
NA.22
MDL number:
MFCD00064810

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 97%

SMILES string

[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F

InChI

1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1

InChI key

GNQXUMGHBSAQBV-UHFFFAOYSA-N

assay

97%

form

solid

mp

160 °C (dec.) (lit.)

reaction suitability

reagent type: catalyst
reagent type: catalyst
core: copper
reaction type: click chemistry

Quality Level

100

Related Categories

Application

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.


It can also be used as a copper precursor:


  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
  • In the synthesis of stimuli-responsive particle-based amphiphiles prepared by anisotropic click chemistry.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCX8961
MKCW6301
0000315505
0000315505
0000242952

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.
Stark HS, et al.
Inorganic Chemistry, 28(9), 095705-095705 (2018)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Diez-Gonzalez S, et al.
Chemistry?A European Journal , 14(1), 158-168 (2008)
Tetrakis (acetonitrile) copper (I) Hexafluorophosphate as an Efficient Catalyst for the Synthesis of Triazolo [1, 2-a] indazole-1, 3, 8-trione and 2Hindazolo [2, 1-b] phthalazine-trione Derivatives.
Azarifar D, et al.
Letters in Organic Chemistry, 9(2), 128-132 (2012)
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Tao XD, et al.
Polyhedron, 144(9), 36-43 (2018)
Biswajit Kundu et al.
Nanotechnology, 28(9), 095705-095705 (2017-01-31)
Through scanning tunneling spectroscopy, we envisage imaging a heterostructure, namely a junction formed in a single nanorod. While the differential conductance spectrum provides location of conduction and valence band edges, dI/dV images record energy levels of materials. Such dI/dV images
View All Related Papers

Articles

What is Click Chemistry? An Introduction

Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service