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804010

Co(salen,t-Bu, t-Bu)Cl

Name: Co(salen,<I>t</I>-Bu, <I>t</I>-Bu)Cl
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₃₆H₅₂ClCoN₂O₂

Molecular Weight:

639.20

PubChem Substance ID:

329768839

UNSPSC Code:

12352300

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Properties

form

powder

reaction suitability

reagent type: catalyst
core: cobalt

mp

250 °C

storage temp.

2-8°C

SMILES string

Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1

InChI

1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1

InChI key

DIPYCKRNYQWVPM-RUIQGICGSA-K

Description

Application

When utilized with organosilanes, catalytic amounts of Co(salen,t-Bu, t-Bu)Cl effects the isomerization of terminal alkenes.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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