394904
Pentafluoropropionic anhydride
derivatization grade (GC derivatization), LiChropur™, 99%
Synonym(s):
PFPA, Perfluoropropionic anhydride
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About This Item
Linear Formula:
(CF3CF2CO)2O
CAS Number:
Molecular Weight:
310.05
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-604-2
Beilstein/REAXYS Number:
1806446
MDL number:
Assay:
99%
Form:
liquid
grade
derivatization grade (GC derivatization)
Quality Segment
assay
99%
form
liquid
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
technique(s)
gas chromatography (GC): suitable
bp
69-70 °C/735 mmHg (lit.)
density
1.571 g/mL at 25 °C (lit.)
SMILES string
FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F
InChI
1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16
InChI key
XETRHNFRKCNWAJ-UHFFFAOYSA-N
Application
Learn more in the Product Information
Derivatization reagent used in a GC-MS analysis of stereoisomer content of synthetic peptides. Also used in a GC-MS detection method for synephrine in dietary supplements.
For the preparation of volatile pentafluoropropionyl derivatives of a wide range of compounds, for example, amines and alcohols, for EC/GC.
Pentafluoropropionic anhydride (PFPA) was used as derivatization reagent for urine samples to determine the presence of codeine, morphine, 6-monoacetylmorphine, ethylmorphine, and dihydrocodeine using GC-MS in selected ion monitoring (SIM) mode. It was also used to derivatize the dry pericardial fluid sample extracts for quantification of cocaine, benzoylecgonine, and cocaethylene in pericardial fluid using GC-MS.
Packaging
Clear borosilicate glass, high hydrolytic resistance (Type I)
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
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signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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